[Cu(1-(3-[1,10]phenanthrolin-2-ylphenyl)-3-(4-trifluoromethylphenyl)urea)2](ClO4) | 889063-19-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Cu(1-(3-[1,10]phenanthrolin-2-ylphenyl)-3-(4-trifluoromethylphenyl)urea)2](ClO4)
• CAS: 889063-19-8
• 化学式: C₅₂H₃₄CuF₆N₈O₂*ClO₄
• 分子量: 1079.88
• InChiKey: VUMACCWUDMVGBA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I) perchlorate 、 1-(3-[1,10]phenanthrolin-2-yl-phenyl)-3-(4-trifluoromethylphenyl)urea 以 甲醇 、 二氯甲烷 为溶剂， 以99%的产率得到[Cu(1-(3-[1,10]phenanthrolin-2-ylphenyl)-3-(4-trifluoromethylphenyl)urea)2](ClO4)
  参考文献：
  名称：

  Metal-Controlled Assembly and Selectivity of a Urea-Based Anion Receptor

  摘要：

  1-( 3-[ 1,10] phenanthrolin-2-yl-phenyl)-3-( 4-trifluoromethyl-phenyl)-urea ( 1) forms a solution-stable 1:2 complex with copper( I), [ Cu-I( 1)(2)](+), which behaves as an anion receptor in aprotic media. The [ Cu-I( 1)(2)](+) receptor may adopt a geometrical arrangement in which the two facing urea subunits give tetrafurcate H-bond interaction with a spherical anion ( halides and H2PO4-). In the presence of the Y-shaped acetate, the [ Cu-I(1)(2)](+) receptor rearranges to interact with two CH3COO- ions, according to two stepwise equilibria. Thus, in the presence of substoichiometric amounts of the anions, [ Cu-I( 1)(2)](+) discriminates H2PO4- over CH3COO-, inverting the basicity trend.

  DOI：

  10.1021/ic060160x