[Au(bis(methyldiphenylphosphonio)methylide)C6F5]CF3SO3 | 308273-96-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: [Au(bis(methyldiphenylphosphonio)methylide)C6F5]CF3SO3
• CAS: 308273-96-3
• 化学式: CF₃O₃S*C₃₃H₂₇AuF₅P₂
• 分子量: 926.554
• InChiKey: CMQYAYWBUZRCMA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  pentafluorophenyl(tetrahydrothiophene)gold(I) 、 [bis(methyldiphenylphosphonio)methylide]CF3SO3 以 二氯甲烷 为溶剂， 以87%的产率得到[Au(bis(methyldiphenylphosphonio)methylide)C6F5]CF3SO3
  参考文献：
  名称：

  Gold(I) complexes containing the cationic ylide ligand bis(methyldiphenylphosphonio)methylide

  摘要：

  The ylide Ph2PCH=PPh2Me can be selectively P-alkylated by Mel or MeO3SCF3 to form the bis(methyldiphenylphosphonio)methylide salts [MePPh2CHPPh2Me]A (A=I (1), CF3SO3 (2)). The ylidic carbon shows a weak nucleophilicity and does not give typical reactions with common organic electrophiles, including Wittig type reactions, but it is able to displace tetrahydrothiophene in [AuX(tht)] to give the corresponding C-coordinated gold(I) compounds [Au{CH(PPh2Me)(2)}X]CF3SO3 (X=Cl (3), C6F5 (4)). The crystal structure of (4) displays a linear coordination for the gold atom, single P-C bond lengths and a PCP angle of 119.1(3)degrees for the ligand. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00467-8