Rh(TPP)CH2OPh | 344791-33-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Rh(TPP)CH2OPh
• CAS: 344791-33-9
• 化学式: C₅₁H₃₅N₄ORh
• 分子量: 822.771
• InChiKey: QFLWIAJIBIZAHK-YKKPBKTHSA-N

反应信息

• 作为产物：
  描述：

  Rh2(CO)4(TPP) 、 苯甲醚 以85%的产率得到Rh(TPP)CH2OPh
  参考文献：
  名称：

  Aromatic and Benzylic C−H Bond Activation in the System Bis(dicarbonylrhodium(I))- porphyrinate−Hydrocarbon Solvent

  摘要：

  Metalation of C6H6 has been known for a long time as a side reaction occurring in refluxing benzene solutions of Rh-2(CO)(4)(TPP) (TTP = tetraphenylporphyrin). Rather than representing the intrinsic reactivity of this complex, such hydrocarbon activation proceeds via Rh-II(por) and Rh-III(por) derivatives resulting from oxidation of Rh-2(CO)(4)(TPP) with adventitious H2O and/or O-2. This reaction can be extended to other aromatic substrates and represents an efficient synthetic route to certain organometallic Rh-III(TPP) derivatives.[GRAPHICS]

  DOI：

  10.1021/ic0011112