tris-[2-(2-methyl-acryloyloxy)-ethoxy]-[1,3,5]triazine | 55008-64-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: tris-[2-(2-methyl-acryloyloxy)-ethoxy]-[1,3,5]triazine
• 英文别名: 2-[[4,6-Bis[2-(2-methylprop-2-enoyloxy)ethoxy]-1,3,5-triazin-2-yl]oxy]ethyl 2-methylprop-2-enoate
• CAS: 55008-64-5
• 化学式: C₂₁H₂₇N₃O₉
• 分子量: 465.46
• InChiKey: KUAQSOGWUUACLV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  33
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  145
• 氢给体数：
  0
• 氢受体数：
  12

文献信息

• Curable coating composition
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0100688A2

  公开（公告）日：1984-02-15

  A curable coating composition is composed of (A) 100 parts by weight of an acryloyl- or methacryloyl-oxyalkyl cyanurate or isocyanurate compound of the following formula (I) or (l) wherein X', X2 and X3 represent hydrogen, C1-C4 alkyl, acryloyl or methacryloyl such that at least two of X1, X2 and X3 are selected from acryloyl or methacryloyl and R1, R2 and R3 represent oxyalkylene or poly(oxyalkylene), (B) more than 0 to 1,000 parts by weight of (b,) a polyacrylate or polymethacrylate with a number average molecular weight of 240 to 3,000 of an oxy- or polyoxyalkanepolyol containing 1 or more ether linkages and 3 or more hydroxyl groups per molecule, or (b2) a poly(meth)acrylate of an alkanepolyol having 4 or more hydroxyl groups per molecule, (C) 0.01 to 20 parts by weight, per 100 parts by weight of the components (A) and (B), of a polymerization initiator capable of curing said components, and (D) 0 to 200 parts by weight per 100 parts by weight of the components (A) and (B), of an inorganic solid filler. The composition can be used to coat plastics, metallic or ceramic articles.

  可固化涂层组合物由以下成分组成 (A) 100 份重量的丙烯酰基或甲基丙烯酰基氧基烷基氰尿酸酯或异氰尿酸酯下式 (I) 或 (l) 化合物 其中 X'、X2 和 X3 代表氢、C1-C4 烷基、丙烯酰基或甲基丙烯酰基，这样 X1、X2 和 X3 中至少有两个选自丙烯酰基或甲基丙烯酰基，R1、R2 和 R3 代表氧亚烷基或聚氧亚烷基、 (B) 0 至 1,000 份（按重量计）以上的(b,)聚丙烯酸酯或聚甲基丙烯酸酯，其平均 分子量为 240 至 3,000 份，该聚丙烯酸酯或聚甲基丙烯酸酯为含 1 个或更多醚键且 每分子含 3 个或更多羟基的氧基或聚氧烷多元醇，或(b2)每分子含 4 个或更多羟基 的烷多元醇的聚(甲基)丙烯酸酯、 (C) 按每 100 份组分（A）和（B）的重量计，加入 0.01 至 20 份可固化上述组分的聚合引发剂，以及 (D) 以每 100 份组分（A）和（B）的重量计，0 至 200 份无机固体填料。该组合物可用于塑料、金属或陶瓷制品的涂层。
• Crystalline 1-butene polymer composition
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0171976A1

  公开（公告）日：1986-02-19

  A crystalline 1-butene polymer composition which can be formed into piping or pipe linings comprises (a) a crystalline 1-butene polymer composed of 1-butene as the main component, and (b) from 0.2 to 100 parts by weight, per 100 parts by weight of the crystalline 1-butene polymer (a), of a radical-treated crystalline olefin polymer (1) having a boiling p-xylene-insoluble content of at most 30% by weight and (2) satisfying the following expression wherein TcCL is the crystallization temperature (°C) of the radical-treated crystalline olefin polymer and TcO is the crystallization temperature of the crystalline olefin polymer before the radical treatment.

  一种可制成管道或管道衬里的结晶 1-丁烯聚合物组合物包括 (a) 以 1-丁烯为主要成分的结晶 1-丁烯聚合物，和 (b) 以每 100 份结晶 1-丁烯聚合物 (a) 重量计，0.2 至 100 份经自由基处理的结晶烯烃聚合物 (1)，其沸点对二甲苯不溶物含量不超过 30%（以重量计），且 (2)满足以下表达式 其中，TcCL 是经自由基处理的结晶烯烃聚合物的结晶温度（℃），TcO 是经自由基处理前结晶烯烃聚合物的结晶温度。
• HARDENABLE COATING RESIN COMPOSITION, COATED MATERIALS AND CONTAINERS, AND PROCESS FOR PRODUCING THEM
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0754736A1

  公开（公告）日：1997-01-22

  A surface-coated vessel or a surface-coated product having a hard coating layer is obtained, by coating a substrate of, for example, resin product with a resin composition for hard coating which comprises (a) a poly[(meth)acryloyloxyalkyl] (iso)cyanurate represented by the following general formula (1) or (2): wherein X1, X2 and X3 are each an acryloyl group, methacryloyl group, hydrogen atom or an alkyl group, with a proviso that at least two of them are (meth)acryloyl groups, and R1, R2 and R3 are each an oxyalkylene group or a polyoxyalkylene group; (b) a poly(meth)acrylated polyoxyalkane polyol; (c) a photopolymerization initiator consisting of 2-methyl-1-[4-(methylthio)phenyl]-2-morpholino-1-propanone; (d) a photopolymerization initiator based on thioxanthone; (e) a UV-absorber based on monohydroxybenzophenone; (f) an organic solvent. Such surface-coated products and vessels have a hard coat which is more excellent than that of the prior art especially in the curing characteristics, such as the rate of curing etc., as well as in the coating properties, such as surface hardness, fastness to scratch and abrasion, flexibility, surface gloss, heat resistance, fastness to solvents and to alkali, weather resistance and tight adhesion onto substrates, so that they can constitute reclamable coated products in a form of, for example, returnable bottles.

  在树脂产品等基材上涂覆硬涂层用树脂组合物，可获得具有硬涂层的表面涂层容器或表面涂层产品，该组合物包括 (a) 由以下通式（1）或（2）表示的聚[（甲基）丙烯酰氧基烷基]（异）氰尿酸酯： 其中 X1、X2 和 X3 各为丙烯酰基、甲基丙烯酰基、氢原子或烷基，但其中至少有两个为（甲基）丙烯酰基，而 R1、R2 和 R3 各为氧亚烷基或聚氧亚烷基； (b) 聚(甲基)丙烯酰化聚氧烷基多元醇； (c) 由 2-甲基-1-[4-(甲硫基)苯基]-2-吗啉基-1-丙酮组成的光聚合引发剂； (d) 一种基于硫黄酮的光聚合引发剂； (e) 基于单羟基二苯甲酮的紫外线吸收剂； (f) 有机溶剂。 这种表面涂层产品和容器具有比现有技术更优异的硬涂层，特别是在固化特性（如固化速度等）以及涂层性能（如表面硬度、耐刮擦和耐磨性、柔韧性、表面光泽、耐热性、耐溶剂和耐碱性、耐候性和与基材的紧密粘合性）方面，因此它们可以构成例如可回收瓶子形式的可回收涂层产品。
• The preparation of a pixel sheet provided with black matrix
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0821275A2

  公开（公告）日：1998-01-28

  A pixel sheet provided with black matrix is prepared by the steps of: preparing a pixel sheet by forming pixels on a light-transmissive support under the condition that a space area is left between the pixels; covering the pixels and the space area of the pixel sheet with a photosensitive black resin layer; exposing to light the pixel sheet having the black resin layer on the side of the support; bringing the light-exposed pixel sheet in contact with a developing solution to peel the black resin layer on the pixels off, while keeping the black resin layer on the support in the space area; and heating the developed pixel sheet so that the black resin layer in the space area is fully cured.

  一种带有黑色矩阵的像素片是通过以下步骤制备的：在透光支架上形成像素，并在像素之间留出空间区域，以此制备像素薄片；在像素和像素薄片的空间区域上覆盖感光黑色树脂层；将在支架一侧具有黑色树脂层的像素薄片对光照射；将对光照射的像素薄片与显影液接触，以剥离像素上的黑色树脂层，同时在空间区域内保留支架上的黑色树脂层；加热已显影的像素薄片，使空间区域内的黑色树脂层完全固化。
• PHOTOPOLYMERIZABLE COMPOSITION
  申请人：Kyowa Hakko Chemical Co., Ltd.

  公开号：EP1493757A1

  公开（公告）日：2005-01-05

  The invention provides a photopolymerizable composition having a high photosensitivity, which comprises a metal complex of a squarylium compound, a radical generator, and a compound having at least one ethylenically unsaturated double bond. The photopolymerizable composition of the present invention is advantageously used for a visible laser recording material such as a PS (Presensitized Plate) for laser direct plate-making, a dry film resist, a digital proof, a hologram, or the like, a panchromatic sensitive material (e.g., a sensitive material for a color hologram and a sensitive material used for full-color display and containing a photopolymerizable composition in a microcapsule), paints, adhesives, and so on.

  本发明提供了一种具有高光敏性的可光聚合组合物，它由鳞片化合物的金属复合物、自由基发生器和至少具有一个乙烯不饱和双键的化合物组成。 本发明的可光敏聚合组合物可以很好地用于可见激光记录材料，如用于激光直接制版的 PS（预感光板）、干膜抗蚀剂、数字打样、全息图或类似材料、全色感光材料（例如，用于彩色全息图的感光材料和用于全色显示并在微胶囊中含有可光敏聚合组合物的感光材料）、涂料、粘合剂等。