[Cu(N,N'-bis[4-(hexadecyloxy)salicylidene]ethylenediamine)] | 697737-65-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Cu(N,N'-bis[4-(hexadecyloxy)salicylidene]ethylenediamine)]
• CAS: 697737-65-8
• 化学式: C₄₈H₇₈CuN₂O₄
• 分子量: 810.704
• InChiKey: GBICQDROZXPXBJ-QYLGTZOCSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper diacetate 、 N,N'-bis[4-(hexadecyloxy)salicylidene]ethylenediamine 以 甲醇 、 氯仿 为溶剂， 生成 [Cu(N,N'-bis[4-(hexadecyloxy)salicylidene]ethylenediamine)]
  参考文献：
  名称：

  Second-order non-linear optical response in LB films for the metal complexes

  摘要：

  The complexes with long alkyl chains ([Fe(C(16)-trz)(3)](ClO(4))(2))(n) (1), [Fe(C(15)-BPT)(2)(NCS)(2)] (2), [Fe(C(16)-salen)Cl] (3), [Fe(C(16)-salmmen)Cl] (4), K[Fe(C(16)-salen)(CN)(2)] (S), K[Fe(C(16)-salmmen)(CN)(2)] (6), Na[Fe(C(16)-salmmen)(CN)(2)] (7), [Mn(C(16)-salen)Cl] (8), [Ni(C(16)-salen)] (9), [Cu(C(16)-salen)] (10) were synthesized (C(16)-trz = 4-hexadecyl-1,2,4-triazole, C(15)-BPT = N-(3,5-di-2-pyridinyl-4H-1,2,4-triazol-4-yl)-hexadecanecarboxamide, C(16)-salen = N,N-bis[4-(hexadecyloxy)salicylidene]ethylenediamine, C(16)-salmmen = N,N'-bis[4-(hexadecyloxy)salicylidene]-1,2-diaminopropane). Langmuir-Blodgett (LB) films of compounds 1-10 were prepared (Scheme 1). The transfers of the molecules from onto the gas-water surface to glass substrate were confirmed by UV-Vis spectra. The second harmonic generation (SHG) were estimated for the LB films formed by the metal complexes. The SHG was observed for the complexes with the long alkyl chains in LB film. The order of the intensity for the SHG related with the number of unpaired d electrons or the d electron configurations. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.10.059