bis[μ-3,5-bis(trifluoromethyl)pyrazolato]bis(2,4,6-collidine)disilver(I) | 647861-75-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: bis[μ-3,5-bis(trifluoromethyl)pyrazolato]bis(2,4,6-collidine)disilver(I)
• 英文别名: [silver(I)(3,5-bis(trifluoromethyl)pyrazole(1-))2(2,4,6-collidine)2]；{[3,5-(CF3)2Pz]Ag(collidine)}2；disilver;3,5-bis(trifluoromethyl)pyrazol-2-ide;2,4,6-trimethylpyridine
• CAS: 647861-75-4
• 化学式: C₂₆H₂₄Ag₂F₁₂N₆
• 分子量: 864.234
• InChiKey: CKMLXIRTGKYIKU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.16
• 重原子数：
  46
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  53.6
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  2,4,6-三甲基吡啶 、 tris[3,5-bis(trifluoromethyl)pyrazolato]trisilver(I) 以 not given 为溶剂， 生成 bis[μ-3,5-bis(trifluoromethyl)pyrazolato]bis(2,4,6-collidine)disilver(I)
  参考文献：
  名称：

  Blue Phosphors of Dinuclear and Mononuclear Copper(I) and Silver(I) Complexes of 3,5-Bis(trifluoromethyl)pyrazolate and the Related Bis(pyrazolyl)borate

  摘要：

  The synthesis, structure, and photoluminescence properties are described for the three-coordinate mononuclear and dinuclear complexes [H2B(3,5-(CF3)(2)PZ)(2)]M(2,4,6-collidine), M-1, and {[3,5-(CF3)(2)Pz]M(2,4,6-collidine)}(2), M-2, respectively (M = Cu; Ag). The solids exhibit bright blue phosphorescence, at room temperature for the copper compounds and at 77 K for all compounds. Ag-1, Cu-1, and Cu-2 exhibit blue pyrazole-based structured emissions with short phosphorescence lifetimes, 10(1)-10(2) mus, due to an internal heavy-metal effect. Meanwhile, Ag-2 exhibits curious multiple excitation-dependent emissions.

  DOI：

  10.1021/ic0347586