2-((anthracen-9-ylmethyl)(2-hydroxyethyl)amino)-N-ethylacetamide | 1253424-07-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2-((anthracen-9-ylmethyl)(2-hydroxyethyl)amino)-N-ethylacetamide
• 英文别名: 2-[anthracen-9-ylmethyl(2-hydroxyethyl)amino]-N-ethylacetamide
• CAS: 1253424-07-5
• 化学式: C₂₁H₂₄N₂O₂
• 分子量: 336.434
• InChiKey: YYOXZWYNFPKXLO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  25
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  52.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-(anthracen-9-ylmethyl)morpholin-2-one 、 乙胺 以 四氢呋喃 为溶剂， 反应 4.0h， 以90%的产率得到2-((anthracen-9-ylmethyl)(2-hydroxyethyl)amino)-N-ethylacetamide
  参考文献：
  名称：

  Selective sensing of Zn(II) ion by a simple anthracene-based tripodal chemosensor

  摘要：

  A new and an easy-to-make simple tripodal shaped chemosensor 1, comprising an anthracene moiety as a fluorophore and amide, alcohol functionalities as ligating groups has been designed and synthesized for Zn(II). In CH3CN containing 0.1% DMSO, upon excitation at 370 nm, the chemosensor 1 exhibited an emission at 412 nm, which increased to a large extent upon complexation of Zn(II). Among the other metal ions examined in the study, Cd2+ moderately perturbed the emission of 1 under similar conditions. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.07.070

文献信息

• Selective sensing of Zn(II) ion by a simple anthracene-based tripodal chemosensor
  作者：Kumaresh Ghosh、Indrajit Saha

  DOI：10.1016/j.tetlet.2010.07.070

  日期：2010.9

  A new and an easy-to-make simple tripodal shaped chemosensor 1, comprising an anthracene moiety as a fluorophore and amide, alcohol functionalities as ligating groups has been designed and synthesized for Zn(II). In CH3CN containing 0.1% DMSO, upon excitation at 370 nm, the chemosensor 1 exhibited an emission at 412 nm, which increased to a large extent upon complexation of Zn(II). Among the other metal ions examined in the study, Cd2+ moderately perturbed the emission of 1 under similar conditions. (C) 2010 Elsevier Ltd. All rights reserved.