[Cu(OAc)(1,2-aminobenzylamine)2][OAc] | 1238148-42-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(OAc)(1,2-aminobenzylamine)2][OAc]
• CAS: 1238148-42-9
• 化学式: C₂H₃O₂*C₁₆H₂₃CuN₄O₂
• 分子量: 425.975
• InChiKey: PFFJGRBWDUJPCD-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  2-氨基苄胺 、 copper(II) acetate monohydrate 以 四氢呋喃 为溶剂， 生成 [Cu(OAc)(1,2-aminobenzylamine)2][OAc]
  参考文献：
  名称：

  Synthesis and catalytic activity of novel Zn–N and Cu–N complexes

  摘要：

  A series of zinc and copper complexes supported by 1, 3-diaminobenzene, 1, 2-aminobenzylamine, 1, 3-aminobenzylamine and m-xylylenediamine was synthesized and characterized. Reaction of 1, 3-diaminobenzene, 1, 2-aminobenzylamine, 1, 3-aminobenzylamine and m-xylylenediamine with Zn (OAc)(2)center dot 2H(2)O and Cu(OAc)(2)center dot H2O in alcohol, methanol or tetrahydrofuran resulted in the production of five novel zinc and copper complexes: 2, 4, 6, 8 and 9. Moreover, the structure of each of complex was determined by X-ray diffraction analysis. Every complex was also characterized by elemental analysis, H-1 NMR and IR. The complexes were then used to catalyze the Henry reaction and good catalytic results (65-99%) were achieved. The catalytic activity of the complexes was determined by H NMR. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.05.017