9,10-dihydro-9,10-ethenoanthracene-2,3,6,7-tetracarboxylic acid tetramethyl ester | 1134642-55-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,10-dihydro-9,10-ethenoanthracene-2,3,6,7-tetracarboxylic acid tetramethyl ester
• 英文别名: Tetramethyl tetracyclo[6.6.2.02,7.09,14]hexadeca-2,4,6,9,11,13,15-heptaene-4,5,11,12-tetracarboxylate；tetramethyl tetracyclo[6.6.2.02,7.09,14]hexadeca-2,4,6,9,11,13,15-heptaene-4,5,11,12-tetracarboxylate
• CAS: 1134642-55-9
• 化学式: C₂₄H₂₀O₈
• 分子量: 436.418
• InChiKey: WMFFGSADKJASJZ-UHFFFAOYSA-N

物化性质

• 沸点：
  542.6±50.0 °C(Predicted)
• 密度：
  1.332±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  32
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  9,10-dihydro-9,10-ethenoanthracene-2,3,6,7-tetracarboxylic acid tetramethyl ester 在 二异丁基氢化铝 作用下， 以 甲苯 为溶剂， 以92%的产率得到9,10-dihydro-2,3,6,7-tetrakis(hydroxymethyl)-9,10-ethenoanthracene
  参考文献：
  名称：

  Iterative synthesis of acenesvia homo-elongation

  摘要：

  从芳香邻二醛出发，我们设计了一套同系延长方案，结合了Wittig烯化反应和随后的分子内Knoevenagel缩合反应，以生成并五烷二酯和二腈。

  DOI：

  10.1039/b814840f
• 作为产物：
  描述：

  5,6,7,8-四(亚甲基)-双环[2.2.2]-2-辛烯 、 丁炔二酸二甲酯 在 四氯苯醌 作用下， 以 甲苯 为溶剂， 以93%的产率得到9,10-dihydro-9,10-ethenoanthracene-2,3,6,7-tetracarboxylic acid tetramethyl ester
  参考文献：
  名称：

  Iterative synthesis of acenesvia homo-elongation

  摘要：

  从芳香邻二醛出发，我们设计了一套同系延长方案，结合了Wittig烯化反应和随后的分子内Knoevenagel缩合反应，以生成并五烷二酯和二腈。

  DOI：

  10.1039/b814840f

文献信息

• Mechanochromic luminescent material, mechanochromic resin obtained by crosslinking mechanochromic luminescent material, method for producing mechanochromic luminescent material, and method for producing mechanochromic
  申请人：JAPAN SCIENCE AND TECHNOLOGY AGENCY

  公开号：US10442886B2

  公开（公告）日：2019-10-15

  Provided is a mechanochromic resin by which a stress applied to a material can be visualized in real time, and a mechanochromic luminescent material that is used in the synthesis of the mechanochromic resin. Stress can be visualized in real time by means of a mechanochromic luminescent material represented by formula (1) or formula (2) and a mechanochromic resin obtained by crosslinking the mechanochromic luminescent material. [Chemical formula 1] (In the formula, Y1 and Y2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (1), and Y1 and Y2 may be same as or different from each other. Z1 and Z2 each denote a polymerizable group, and may be same as or different from each other.) [Chemical formula 2] (In the formula, Y1 and Y2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (2), and Y1 and Y2 may be same as or different from each other. Z1 and Z2 each denote a polymerizable group, and may be same as or different from each other).

  提供一种机械致变色树脂，可实时可视化材料受到的应力，以及用于合成机械致变色树脂的机械致发光材料。通过公式（1）或公式（2）所表示的机械致发光材料和交联该机械致发光材料所得到的机械致变色树脂，可以实时可视化应力。【化学式1】（在公式中，Y1和Y2分别表示抑制公式（1）所表示的机械致发光材料聚集的取代基，Y1和Y2可以相同也可以不同。Z1和Z2分别表示可聚合基团，可以相同也可以不同。）【化学式2】（在公式中，Y1和Y2分别表示抑制公式（2）所表示的机械致发光材料聚集的取代基，Y1和Y2可以相同也可以不同。Z1和Z2分别表示可聚合基团，可以相同也可以不同。）
• MECHANOCHROMIC LUMINESCENT MATERIAL, MECHANOCHROMIC RESIN OBTAINED BY CROSSLINKING MECHANOCHROMIC LUMINESCENT MATERIAL, METHOD FOR PRODUCING MECHANOCHROMIC LUMINESCENT MATERIAL, AND METHOD FOR PRODUCING MECHANOCHROMIC
  申请人：JAPAN SCIENCE AND TECHNOLOGY AGENCY

  公开号：US20190031820A1

  公开（公告）日：2019-01-31

  Provided is a mechanochromic resin by which a stress applied to a material can be visualized in real time, and a mechanochromic luminescent material that is used in the synthesis of the mechanochromic resin. Stress can be visualized in real time by means of a mechanochromic luminescent material represented by formula (1) or formula (2) and a mechanochromic resin obtained by crosslinking the mechanochromic luminescent material. [Chemical formula 1] (In the formula, Y 1 and Y 2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (1), and Y 1 and Y 2 may be same as or different from each other. Z 1 and Z 2 each denote a polymerizable group, and may be same as or different from each other.) [Chemical formula 2] (In the formula, Y 1 and Y 2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (2), and Y 1 and Y 2 may be same as or different from each other. Z 1 and Z 2 each denote a polymerizable group, and may be same as or different from each other.)
• Iterative synthesis of acenesvia homo-elongation
  作者：Chih-Hsiu Lin、Ke-Han Lin、Bikash Pal、Li-Der Tsou

  DOI：10.1039/b814840f

  日期：——

  Starting from aromaticortho-dialdehydes, we devised a homo-elongation protocol that combines a Wittig olefination and subsequent intramolecular Knoevenagel condensation to produce acene diesters and dinitriles.

  从芳香邻二醛出发，我们设计了一套同系延长方案，结合了Wittig烯化反应和随后的分子内Knoevenagel缩合反应，以生成并五烷二酯和二腈。