N-<(Benzotriazolyl)methyl>butylamine | 142920-55-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并三唑类
• 英文名称: N-<(Benzotriazolyl)methyl>butylamine
• 英文别名: N-(benzotriazol-1-ylmethyl)butan-1-amine
• CAS: 142920-55-6
• 化学式: C₁₁H₁₆N₄
• 分子量: 204.275
• InChiKey: LHMNPTNOZRFTSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  42.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-甲基吡咯 、 N-<(Benzotriazolyl)methyl>butylamine 在 zinc(II) chloride 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以62%的产率得到Butyl[(1-methyl-1H-pyrrol-2-yl)methyl]amine
  参考文献：
  名称：

  Aminoalkylbenzotriazoles: reagents for the aminoalkylation of electron rich heterocycles

  摘要：

  Secondary and tertiary aminoalkylbenzotriazoles react with pyrrole, indole, their N-methyl analogs and with 2-methylfuran under mild reaction conditions in the presence of a Lewis acid to afford selectively the corresponding secondary or tertiary amines.

  DOI：

  10.1016/s0040-4020(01)81590-8
• 作为产物：
  描述：

  T406石油添加剂 、 聚合甲醛 、 正丁胺 在 水 作用下， 以 乙醚 为溶剂， 反应 3.0h， 以91%的产率得到N-<(Benzotriazolyl)methyl>butylamine
  参考文献：
  名称：

  Aminoalkylbenzotriazoles: reagents for the aminoalkylation of electron rich heterocycles

  摘要：

  Secondary and tertiary aminoalkylbenzotriazoles react with pyrrole, indole, their N-methyl analogs and with 2-methylfuran under mild reaction conditions in the presence of a Lewis acid to afford selectively the corresponding secondary or tertiary amines.

  DOI：

  10.1016/s0040-4020(01)81590-8

文献信息

• METHOD FOR PRODUCING METAL PARTICLE DISPERSION, CONDUCTIVE INK USING METAL PARTICLE DISPERSION PRODUCED BY SUCH METHOD, AND CONDUCTIVE COATING FILM
  申请人：Toyo Ink Mfg. Co., Ltd

  公开号：EP1952918B1

  公开（公告）日：2013-05-22
• Refrigerating Machine Oil Composition
  申请人：Tagawa Kazuo

  公开号：US20070257229A1

  公开（公告）日：2007-11-08

  The refrigerating machine oil composition of the present invention contains a polyol ester as a base oil, a phosphorothionate, a phosphorus-based additive other than said phosphorothionate, and a glycidyl ester epoxy compound. With the refrigerating machine oil composition of the present invention, a high level can be attained for both lubricity and stability in a refrigerating/air conditioning apparatus in which an HFC refrigerant or the like is used, and the refrigerating or air-conditioning apparatus can be stably operated over an extended period.
• Refrigerating Machine Oil
  申请人：Tagawa Kazuo

  公开号：US20070275865A1

  公开（公告）日：2007-11-29

  The refrigerating machine oil of the present invention contains a mineral oil whose nitrogen content is not more than 50 ppm by mass and whose percent in aromatic ring structures (% C A ) is from 5 to 25. With the refrigerating machine oil of the present invention, high levels of lubricity, stability, and miscibility with refrigerants are attained, with a good balance between these, so refrigerating and air conditioning machines can be operated stably over a longer period.
• US8083965B2
  申请人：——

  公开号：US8083965B2

  公开（公告）日：2011-12-27
• Aminoalkylbenzotriazoles: reagents for the aminoalkylation of electron rich heterocycles
  作者：Alan R. Katritzky、Zhijun Yang、Jamshed N. Lam

  DOI：10.1016/s0040-4020(01)81590-8

  日期：1992.6

  Secondary and tertiary aminoalkylbenzotriazoles react with pyrrole, indole, their N-methyl analogs and with 2-methylfuran under mild reaction conditions in the presence of a Lewis acid to afford selectively the corresponding secondary or tertiary amines.