(C5Me5)RhCl2(2-telluraindane) | 191487-87-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: (C5Me5)RhCl2(2-telluraindane)
• 英文别名: dichlororhodium(1+);1,3-dihydro-2-benzotellurophene;1,2,3,4,5-pentamethylcyclopenta-1,3-diene
• CAS: 191487-87-3
• 化学式: C₁₈H₂₃Cl₂RhTe
• 分子量: 540.792
• InChiKey: AZQVVZFAVXZFGA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 苯并[c]碲 以 甲苯 为溶剂， 以62%的产率得到(C5Me5)RhCl2(2-telluraindane)
  参考文献：
  名称：

  Badyal, Karanbir; McWhinnie, William R.; Chen, Hong Li, Journal of the Chemical Society, Dalton Transactions, 1997, # 9, p. 1579 - 1585

  摘要：

  DOI：

文献信息

• The synthesis and NMR spectroscopic examination of coordination complexes of 2-telluraindane with rhodium
  作者：Karanbir Badyal、William R McWhinnie、John Homer、Michael C Perry

  DOI：10.1016/s0022-328x(98)00380-5

  日期：1998.3

  Rhodium complexes of 2-telluraindane were synthesised and the nature of metal-ligand interactions in solution were studied using NMR spectroscopy. Two complexes were prepared; [(Cp*Rh)(C8H8Te)][O3SCF3](2) (1) was prepared by the reaction of [Cp*RhCl2](2) with 2-telluraindane in the presence of silver triflate while [(Cp*RhCl2)(C8H8Te)] (2) was synthesised by a direct reaction between the rhodium dimer and the ligand. Complex 1 gives a Te-125 coordination shift of + 260 ppm and a Te-125-Rh-103 coupling constant of 65.9 Hz implying that the metal is directly bonded to the tellurium in the ligand and not to the aryl ring (i.e eta(1) not eta(6) coordination is envisaged). The observation of an AB quartet for the methylene protons (J(AB) = 16 Hz) is as expected for 2-telluraindane coordinated in this manner. In contrast, complex 2 shows a broad singlet for these methylene protons at room temperature (r.t.) which sharpens on heating to 323 K and resolves into the expected AB quartet (J(AB) = 13.5 Hz) on cooling to 223 K, however the Te-125 spectrum is a singlet at r.t. but resolves into a doublet at 238 K (J(103)Rh-Te-125 = 108 Hz). It is argued that these data are only reconcilable in terms of a dissociative mechanism in which the equilibrium populations of the free species are small and where the rate of exchange at r.t. lies between that required to average the Te-125 chemical shifts and that required to effectively decouple the Te-125-Rh-103 interaction. (C) 1998 Elsevier Science S.A. All rights reserved.