| 1221629-03-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1221629-03-3
• 化学式: C₂₉H₃₄N₂O₄*C₂₉H₃₅N₂O₄*Ce*Cl*Cu
• 分子量: 1189.33
• InChiKey: BAGKZQRXXZRNRX-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  cerous nitrate 、 copper(I) oxide 、 1,3-bis(4-carboxy-2,6-diisopropylphenyl)imidazolium chloride 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Cu₂O: A Versatile Reagent for Base-Free Direct Synthesis of NHC-Copper Complexes and Decoration of 3D-MOF with Coordinatively Unsaturated NHC-Copper Species

  摘要：

  A new, and direct synthetic route for N-heterocyclic carbene (NHC)-copper complexes was disclosed by heating imidazolium halides with Cu2O. The related synthetic procedure was quite simple and the product easily separable from the reaction mixture by simple filtration. Ultimately, this reaction was successfully applied to decorate three-dimensional (3D)-metal organic frameworks (MOFs) with coordinatively unsaturated NHC-copper species.

  DOI：

  10.1021/om900768w