9,10-bis[[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl]anthracene | 872104-47-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 9,10-bis[[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl]anthracene
• 英文别名: 9,10-bis{[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl}anthracene
• CAS: 872104-47-7
• 化学式: C₅₈H₅₆N₄P₂
• 分子量: 871.057
• InChiKey: AWSNKYLFPXRCKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.12
• 重原子数：
  64.0
• 可旋转键数：
  18.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  32.26
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  9,10-bis[[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl]anthracene 、 [Ag(MeCN)₄](ClO₄) 以 二氯甲烷 为溶剂， 以71.09%的产率得到disilver(I)(μ-9,10-bis[[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl]anthracene) perchlorate
  参考文献：
  名称：

  Synthesis, Structure and Spectroscopic Properties of Novel9,10‐Bis{[6‐(diphenylphosphanyl)‐2‐pyridylmethyl]propylaminomethyl}anthracene‐Bridged Group 11 Metal (M = Cu ^I and Ag ^I ) Dinuclear Complexes

  摘要：

  AbstractDinuclear complexes [M2(μ‐BPNNAn)]X2 (M = CuI, X = ClO4– 1, X = BF4– 2; M = AgI, X = BF4– 3, X = ClO4– 4) have been prepared by treating 9,10‐bis{[6‐(diphenylphosphanyl)‐2‐pyridylmethyl]propylaminomethyl}anthracene (BPNNAn) with M(CH3CN)4X in CH2Cl2. The structures of complexes 1, 2 and 3 have been determined by single‐crystal X‐ray diffraction studies. In the complexes, BPNNAn acts as a chelating ligand and two metal ions riding on two bridgehead carbon atoms in the anthracene group leads to the deformation of the anthracenyl ring. The Cu–Arene charge transfer interaction is observed from the nonfluorescent emission of Cu complex 1, while the Ag complex 3 exhibits dual emission at high concentrations in a CH2Cl2 solution. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

  DOI：

  10.1002/ejic.200500050
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 sodium sulfide 作用下， 以 水 、 丙酮 为溶剂， 反应 0.5h， 以100%的产率得到9,10-bis[[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl]anthracene
  参考文献：
  名称：

  Synthesis, Structure and Spectroscopic Properties of Novel9,10‐Bis{[6‐(diphenylphosphanyl)‐2‐pyridylmethyl]propylaminomethyl}anthracene‐Bridged Group 11 Metal (M = Cu ^I and Ag ^I ) Dinuclear Complexes

  摘要：

  AbstractDinuclear complexes [M2(μ‐BPNNAn)]X2 (M = CuI, X = ClO4– 1, X = BF4– 2; M = AgI, X = BF4– 3, X = ClO4– 4) have been prepared by treating 9,10‐bis{[6‐(diphenylphosphanyl)‐2‐pyridylmethyl]propylaminomethyl}anthracene (BPNNAn) with M(CH3CN)4X in CH2Cl2. The structures of complexes 1, 2 and 3 have been determined by single‐crystal X‐ray diffraction studies. In the complexes, BPNNAn acts as a chelating ligand and two metal ions riding on two bridgehead carbon atoms in the anthracene group leads to the deformation of the anthracenyl ring. The Cu–Arene charge transfer interaction is observed from the nonfluorescent emission of Cu complex 1, while the Ag complex 3 exhibits dual emission at high concentrations in a CH2Cl2 solution. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

  DOI：

  10.1002/ejic.200500050