4-[(4-氨基-2,5-二氯苯基)甲基]-2,5-二氯苯胺 | 10586-68-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-[(4-氨基-2,5-二氯苯基)甲基]-2,5-二氯苯胺
• 英文名称: bis-(4-amino-2,5-dichloro-phenyl)-methane
• 英文别名: Bis-(4-amino-2,5-dichlor-phenyl)-methan；2,2',5,5'-tetrachloro-4,4'-diaminodiphenylmethane；Benzenamine, 4,4'-methylenebis(2,5-dichloro-；4-[(4-amino-2,5-dichlorophenyl)methyl]-2,5-dichloroaniline
• CAS: 10586-68-2
• 化学式: C₁₃H₁₀Cl₄N₂
• 分子量: 336.048
• InChiKey: XIBDNYHTUNJEKH-UHFFFAOYSA-N

物化性质

• 沸点：
  464.8±40.0 °C(Predicted)
• 密度：
  1.519±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,5-二氯苯胺 在 potassium cyanide 、 2,5-二氯苯胺 、 乙醇 、 2,5-二氯苯胺盐酸盐 、 溶剂黄146 作用下， 生成 4-[(4-氨基-2,5-二氯苯基)甲基]-2,5-二氯苯胺
  参考文献：
  名称：

  关于氨基乙腈。解离规则，第二部分

  摘要：

  （a）描述了芳基氨基-乙腈和二芳基-氨基乙腈的改良合成。在某些情况下，我们观察到的不是预期的腈，而是结晶的N，N'-亚甲基-双-芳基胺。它们是副产物，但是腈形成的中间体。

  DOI：

  10.1002/hlca.19540370120

文献信息

• Bisimide-ether compounds, compositions containing these compounds, and a method for their production
  申请人：Hitachi, Ltd.

  公开号：EP0004592A1

  公开（公告）日：1979-10-17

  A bisimide-ether compound having the general formula is obtained by reacting an ethylenically unsaturated dicarboxylic acid anhydride, a diamine compound and a phenolic compound having in the molecule at least two hydroxyl groups, or by reacting a prepolymer of the anhydride and diamine compound with the phenolic compound : wherein R, is a group containing at least two carbon atoms, R2 is a group containing at least two carbon atoms, R'2 is a group containing at least two carbon atoms and a carbon-carbon double bond, R3 is an aromatic group, the nitrogen atoms of the imide rings being directly connected to different carbon atoms of the group R1, the carbonyl groups of the imide rings being directly connected to different carbon atoms of the group R2 or R'2, the oxygen atoms between the groups R2 and R3 being directly connected to an aromatic nucleus of the group R3, and n is an integer of zero, one or more than 1.

  将乙烯基不饱和二羧酸酐、二胺化合物和分子中含有至少两个羟基的酚类化合物反应，或将酐和二胺化合物的预聚物与酚类化合物反应，可得到通式为...的双亚胺醚化合物： 其中 R, 是至少含有两个碳原子的基团，R2 是至少含有两个碳原子的基团，R'2 是至少含有两个碳原子和一个碳碳双键的基团，R3 是芳香基团，亚胺环的氮原子直接连接到基团 R1 的不同碳原子上、亚胺环的羰基与基团 R2 或 R'2 的不同碳原子直接相连，基团 R2 和 R3 之间的氧原子与基团 R3 的芳香族核直接相连，n 为 0、1 或 1 以上的整数。
• Process for the manufacture of substituted maleimides
  申请人：Bromine Compounds Ltd.

  公开号：EP0499959A1

  公开（公告）日：1992-08-26

  In a process for the preparation of substituted maleimides the corresponding amines are reacted with maleic anhydride and the thermal imidization of the resulting substituted amic-acids is effected in a mixed apolar/polar aprotic solvent medium in the presence of an acid catalyst, a substantial portion of the apolar solvent is subsequently selectively removed from the reaction mixture and most of the final product is precipitated.

  在制备取代马来酰亚胺的工艺中，相应的胺与马来酸酐反应，在酸催化剂存在下，在极性/极性混合烷基溶剂介质中对生成的取代胺酸进行热酰亚胺化，随后从反应混合物中选择性地除去大部分极性溶剂，沉淀出大部分最终产品。
• New polyurea resins and their preparation and use
  申请人：IHARA CHEMICAL INDUSTRY Co., Ltd.

  公开号：EP0538850A2

  公开（公告）日：1993-04-28

  Polyurea resins having excellent mechanical properties and high heat resistance can be prepared by the reaction of an aromatic polyamine component and an aliphatic polyisocyanate component, in which the aromatic polyamine component is a combination of a first aromatic polyamine compound which is typically a polyoxyalkylene-bis(aminobenzoate) compound and a second aromatic polyamine compound selected from various classes of aromatic polyamine compounds different from the first aromatic polyamine compound, in a specified weight proportion. The polyurea resin can be imparted with further improved heat resistance when the aliphatic polyisocyanate component is a combination of an aliphatic diisocyanate compound and a cyclic trimer of an aliphatic polyisocyanate compound in a specified weight proportion.

  通过芳香族多胺组分和脂肪族多异氰酸酯组分的反应，可以制备出具有优异机械性能和高耐热性的聚脲树脂，其中芳香族多胺组分是第一芳香族多胺化合物（通常为聚氧亚烷基双（氨基苯甲酸酯）化合物）和第二芳香族多胺化合物（选自不同于第一芳香族多胺化合物的各类芳香族多胺化合物）按特定重量比例的组合。当脂肪族多异氰酸酯组分是脂肪族二异氰酸酯化合物和脂肪族多异氰酸酯化合物环状三聚体按特定重量比例的组合时，聚脲树脂的耐热性能可进一步提高。
• Elastic foamed grinder material and method for producing the same
  申请人：——

  公开号：US20030066245A1

  公开（公告）日：2003-04-10

  An elastic foamed grinder material of polyurea series for grinding and/or buffing, which is obtainable by subjecting a composition including a main ingredient component including a polyisocyanate, and a composition comprising an aromatic diamine, a foaming agent, a foam-adjusting agent and a curing catalyst to foaming and curing in the presence of grinder granules, wherein the aromatic diamine is an aromatic diamine oligomer alone or in mixture with an aromatic diamine compound, and a method for producing the grinder material.

  一种用于研磨和/或磨光的聚脲系列弹性发泡研磨材料，可通过将包括聚异氰酸酯在内的主成分组分和包括芳香族二胺、发泡剂、泡沫调节剂和固化催化剂的组合物在研磨颗粒存在下进行发泡和固化而获得，其中芳香族二胺是单独的芳香族二胺低聚物或与芳香族二胺化合物的混合物，以及生产该研磨材料的方法。
• Process for producing polyurea resin
  申请人：IHARA CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0279376B1

  公开（公告）日：1993-11-03