μ-4,5-bis(diphenylphosphino)-9,9-dimethylxanthenebis[(trifluoroacetato)gold(I)] | 1292811-40-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: μ-4,5-bis(diphenylphosphino)-9,9-dimethylxanthenebis[(trifluoroacetato)gold(I)]
• CAS: 1292811-40-5
• 化学式: C₄₃H₃₂Au₂F₆O₅P₂
• 分子量: 1198.6
• InChiKey: LGLOANVSKBBBFJ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  二氯甲烷 、 silver trifluoroacetate 、 Xantphos[AuCl]₂ 以 二氯甲烷 为溶剂， 生成 [μ-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene]bis[(trifluoroacetato)gold(I)] - dichloromethane (1/0.58) 、 μ-4,5-bis(diphenylphosphino)-9,9-dimethylxanthenebis[(trifluoroacetato)gold(I)]
  参考文献：
  名称：

  [μ-4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene]bis[(trifluoroacetato)gold(I)] and its dichloromethane 0.58-solvate

  摘要：

  The dinuclear Au-I complex containing the 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (xantphos) ligand and trifluoroacetate anions exists in a solvent-free form, [mu-4,5-bis(diphenylphosphino)-9,9-dimethylxanthene]bis[(trifluoroacetato)gold(I)], [Au-2(C2F3O2)(2)(C39H32OP2)], (I), and as a dichloromethane solvate, [Au-2(C2F3O2)(2)(C39H32OP2)]center dot-0.58CH(2)Cl(2), (II). The trifluoroacetate anions are coordinated to the Au-I centres bridged by the xantphos ligand in both compounds. The Au-I atoms are in distorted linear coordination environments in both compounds. The phosphine substituents are in a syn arrangement in the xantphos ligand, which facilitates the formation of short aurophilic Au center dot center dot center dot Au interactions of 2.8966 (8) angstrom in (I) and 2.9439 (6) angstrom in (II).

  DOI：

  10.1107/s0108270110013363