[tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH2Cl2*water | 1207761-84-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH2Cl2*water
• 英文别名: [Ph4P][trans-Os(III)(CN)2(salen)]*CH2Cl2*H2O
• CAS: 1207761-84-9
• 化学式: CH₂Cl₂*C₁₈H₁₄N₄O₂Os*C₂₄H₂₀P*H₂O
• 分子量: 950.879
• InChiKey: ANKHJVSBMLDHGV-YCVPKDFDSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(N,N',N''-trimethyl-1,4,7-triazacyclononane)(H2O)2](ClO4)2 、 [tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH2Cl2*water 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 以57%的产率得到[Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))][Cu(1,4,7-trimethyl-1,4,7-triazacyclononane)]perchlorate
  参考文献：
  名称：

  trans-[Os^III(salen)(CN)₂]⁻: A New Paramagnetic Building Block for the Construction of Molecule-Based Magnetic Materials

  摘要：

  A novel dicyanoosmium(III) complex, trans-Ph4P[Os-III(salen)(CN)(2)]center dot CH2Cl2 center dot H2O (1; Ph4P+ = tetraphenylphosphonium cation, salen(2-) =N,N'-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me(3)tacn)(H2O)(2)](ClO4)(2) (Me(3)tacn = 1, 4,7-trimethyl-1, 4,7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)(2)](2)[Cu(Me(3)tacn)]center dot CH3OH (2) and [Os(salen)(CN)(2)][CU(Me(3)tacn)] - ClO4 (3).

  DOI：

  10.1021/ic9020178
• 作为产物：
  描述：

  potassium cyanide 、 二氯甲烷 、 Os(III)Cl(PPh3)(N,N'-ethylenebis(salicylideneaminato)) 、 水 、 四苯基氯化膦 以 乙醇 为溶剂， 以32%的产率得到[tetraphenylphosphonium][trans-Os(III)(cyanide)2(N,N'-ethylenebis(salicylideneaminato))]*CH2Cl2*water
  参考文献：
  名称：

  trans-[Os^III(salen)(CN)₂]⁻: A New Paramagnetic Building Block for the Construction of Molecule-Based Magnetic Materials

  摘要：

  A novel dicyanoosmium(III) complex, trans-Ph4P[Os-III(salen)(CN)(2)]center dot CH2Cl2 center dot H2O (1; Ph4P+ = tetraphenylphosphonium cation, salen(2-) =N,N'-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me(3)tacn)(H2O)(2)](ClO4)(2) (Me(3)tacn = 1, 4,7-trimethyl-1, 4,7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)(2)](2)[Cu(Me(3)tacn)]center dot CH3OH (2) and [Os(salen)(CN)(2)][CU(Me(3)tacn)] - ClO4 (3).

  DOI：

  10.1021/ic9020178