[Zn(4,4',6,6'-tetrabromo-2,2-[ethylenedioxybis(nitrilomethylidyne)]diphenol)(H2O)2]n | 1107064-56-1

• 分子结构分类: 有机化合物 - 苯类化合物 - N-苯基羟胺
• 英文名称: [Zn(4,4',6,6'-tetrabromo-2,2-[ethylenedioxybis(nitrilomethylidyne)]diphenol)(H2O)2]n
• CAS: 1107064-56-1
• 化学式: C₁₆H₁₄Br₄N₂O₆Zn
• 分子量: 715.303
• InChiKey: ONRCCVLXPWTRLJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,4',6,6'-tetrabromo-2,2'-[(ethylenedioxy)bis(nitrilomethylidyne)]diphenol 、 zinc(II) acetate dihydrate 以 乙醇 、 丙酮 、 乙腈 为溶剂， 以22.2%的产率得到[Zn(4,4',6,6'-tetrabromo-2,2-[ethylenedioxybis(nitrilomethylidyne)]diphenol)(H2O)2]n
  参考文献：
  名称：

  Synthesis, crystal structure, and properties of supramolecular CuII, ZnII, and CdII complexes with Salen-type bisoxime ligands

  摘要：

  Three new supramolecular complexes, [Cu(L-1)H2O](n) (1), [Zn(L-2)(H2O)(2)](n) (2), and [Cd(L-2)(H2O)(2)](n) (3), have been synthesized and characterized by FT-IR spectra, fluorescence spectra, and thermal analyses. And the structures of complexes 1-3 have been elucidated by X-ray analyses. Complex 1 is square pyramidal geometry with an unusually long bond (2.262 angstrom) from penta-coodinated Cu-II center to the oxygen atom of the apical coordinated water molecule. Molecules are linked by hydrogen bonding between the coordinated water and the phenolic oxygen atoms of adjacent molecules, thus formed a self-assembling continual zigzag chain supramolecular structure. The crystal structure of complex 2 (or 3) has indicated that the complex consists of one Zn-II (or Cd-II) atom, one L-2 unit and two coordinated water molecules, the coordination number of the Zn-II (or Cd-II) atom is six, and formed an infinite metal-water chain supramolecular structure by intermolecular hydrogen bonds and pi-pi stacking of neighboring benzene rings. Meanwhile, the thermal and photophysical properties of the resulted complexes have also been discussed. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.03.128