| 1360933-44-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 1360933-44-3
• 化学式: C₆₅H₅₇N₉O₅S₂Zn
• 分子量: 1173.75
• InChiKey: QIOFNEVZMNPLNM-NZBDOVBPSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 N,N′-(((2-aminoethyl)azanediyl)bis(ethane-2,1-diyl))bis(4-methylbenzenesulfonamide) 在 zinc diacetate 作用下， 以 甲醇 、 氯仿 为溶剂， 反应 0.5h， 生成
  参考文献：
  名称：

  Enhanced Shape-Selective Recognition of Anion Guests through Complexation-Induced Organization of Porphyrin Hosts

  摘要：

  We present a fortuitous discovery of enhanced shape-selective recognition of anion guests that stems from a complexation-induced conformational change in porphyrin hosts upon anion binding. Porphyrin hosts reported here exist in a conformation that is not favorable to guest binding. Anions that bind strongly are those that can induce a conformational change in the host to allow guest binding. Furthermore, guests that mimic the shape of the newly formed pocket bind the strongest.

  DOI：

  10.1021/ol203249x