6-methyl-2,2-diethoxy-1,3,6,2-dioxazagermocane | 1207181-39-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 金属杂环化合物
• 英文名称: 6-methyl-2,2-diethoxy-1,3,6,2-dioxazagermocane
• CAS: 1207181-39-2
• 化学式: C₉H₂₁GeNO₄
• 分子量: 279.86
• InChiKey: ZHNWYRGPJUMVOQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  6-methyl-2,2-diethoxy-1,3,6,2-dioxazagermocane 、 N,N-二羟乙基苯胺 以 甲苯 为溶剂， 以84%的产率得到4-methyl-12-phenyl-1,7,9,15-tetraoxa-4,12-diaza-8-germaspiro[7,7]pentadecane
  参考文献：
  名称：

  Synthesis, structure, and reactivity of germanium-containing derivatives of substituted diethanolamines

  摘要：

  The reaction of dialkanolamines RN(CH2CH2O)(CHR'CHR'OH) (R = Me, Ph, PhCH2; R' = H, Ph) with tetraethoxygermane gives either 2,2-diethoxy-1,3,6,2-dioxazagermocanes RN(CH2CH2O)(CHR'CHR'O) Ge(OEt)(2) or 1,7,9,15-tetraoxa-4,12-diaza-8-germaspiro[7.7] pentadecanes [RN(CH2CH2O) (CHR'CHR'O)](2)Ge depending on the reactant ratio. The chemical behavior of the obtained compounds in substitution reactions at germanium was studied. The product structure was confirmed by elemental analysis data and H-1, C-13, and F-19 NMR spectroscopy. The cyclotrigermanoxane [MeN(CH2CH2O)(2)GeO](3) was studied by X-ray diffraction.

  DOI：

  10.1134/s0036023609020077
• 作为产物：
  描述：

  N-甲基二乙醇胺 、 tetraethoxygermanium 以 甲苯 为溶剂， 以77%的产率得到6-methyl-2,2-diethoxy-1,3,6,2-dioxazagermocane
  参考文献：
  名称：

  Synthesis, structure, and reactivity of germanium-containing derivatives of substituted diethanolamines

  摘要：

  The reaction of dialkanolamines RN(CH2CH2O)(CHR'CHR'OH) (R = Me, Ph, PhCH2; R' = H, Ph) with tetraethoxygermane gives either 2,2-diethoxy-1,3,6,2-dioxazagermocanes RN(CH2CH2O)(CHR'CHR'O) Ge(OEt)(2) or 1,7,9,15-tetraoxa-4,12-diaza-8-germaspiro[7.7] pentadecanes [RN(CH2CH2O) (CHR'CHR'O)](2)Ge depending on the reactant ratio. The chemical behavior of the obtained compounds in substitution reactions at germanium was studied. The product structure was confirmed by elemental analysis data and H-1, C-13, and F-19 NMR spectroscopy. The cyclotrigermanoxane [MeN(CH2CH2O)(2)GeO](3) was studied by X-ray diffraction.

  DOI：

  10.1134/s0036023609020077