2,7-dibromo-9,9-bis[3-(diethoxyphosphoryl)propyl]fluorene | 860021-09-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,7-dibromo-9,9-bis[3-(diethoxyphosphoryl)propyl]fluorene
• 英文别名: 2,7-dibromo-9,9-bis(3'-diethoxylphosphorylpropyl)fluorene；2,7-Dibromo-9,9-bis (3'-diethoxylphosphorylpropyl)-fluorene；2,7-dibromo-9,9-bis(3-diethoxyphosphorylpropyl)fluorene
• CAS: 860021-09-6
• 化学式: C₂₇H₃₈Br₂O₆P₂
• 分子量: 680.351
• InChiKey: BCUQYWLCZAXKBP-UHFFFAOYSA-N

物化性质

• 沸点：
  686.8±45.0 °C(Predicted)
• 密度：
  1.379±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  37
• 可旋转键数：
  16
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  9,9-didodecyl-9H-fluoren-2-ylboronic acid 、 2,7-dibromo-9,9-bis[3-(diethoxyphosphoryl)propyl]fluorene 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 24.0h， 生成 9,9-bis(3'-diethoxylphosphorylpropyl)-2,7-bis(9,9-didodecylfluorene-2-yl)fluorene
  参考文献：
  名称：

  具有膦酸作为荧光离子载体的芴衍生物的荧光传感器：Fe（III）的合成和静态猝灭性质

  摘要：

  一系列含有-PO（OH）新颖芴衍生物的2（1，2），-HS（3）和-N +（CH 3）3（4）的合成和仅膦官能芴衍生物可检测的Fe 3 +对其他金属离子具有高选择性。在水-DMF溶液中滴定Fe 3+进行1和2的荧光猝灭，符合Perrin静态猝灭模型。光谱分析表明Fe 3+通过膦基上的O原子与芴基化学传感器结合形成非荧光配合物。通过Job图估算结合率，并成功监测了样品中的痕量铁。

  DOI：

  10.1016/j.tetlet.2014.05.105
• 作为产物：
  描述：

  2,7-二溴芴 在 四丁基溴化铵 、 sodium hydroxide 作用下， 生成 2,7-dibromo-9,9-bis[3-(diethoxyphosphoryl)propyl]fluorene
  参考文献：
  名称：

  具有膦酸作为荧光离子载体的芴衍生物的荧光传感器：Fe（III）的合成和静态猝灭性质

  摘要：

  一系列含有-PO（OH）新颖芴衍生物的2（1，2），-HS（3）和-N +（CH 3）3（4）的合成和仅膦官能芴衍生物可检测的Fe 3 +对其他金属离子具有高选择性。在水-DMF溶液中滴定Fe 3+进行1和2的荧光猝灭，符合Perrin静态猝灭模型。光谱分析表明Fe 3+通过膦基上的O原子与芴基化学传感器结合形成非荧光配合物。通过Job图估算结合率，并成功监测了样品中的痕量铁。

  DOI：

  10.1016/j.tetlet.2014.05.105

文献信息

• Conjugated microporous polymers bearing phosphonate ligands as an efficient sorbent for potential uranium extraction from high-level liquid wastes
  作者：Meiyun Xu、Xiaoli Han、Tao Wang、Shenhua Li、Daoben Hua

  DOI：10.1039/c8ta02875c

  日期：——

  Conjugated microporous polymers bearing phosphonate ligands are stable and efficient for uranium extraction under highly acidic and strong radioactive conditions.

  带有膦酸配体的共轭微孔聚合物在高度酸性和强放射性条件下稳定且高效地提取铀。
• Ligand-containing conjugated microporous polymer and use thereof
  申请人：SOOCHOW UNIVERSITY

  公开号：US10639613B2

  公开（公告）日：2020-05-05

  The present invention relates to a ligand-containing conjugated microporous polymer, which is obtained by covalent coupling of a conjugated microporous polymer and a uranium complexing ligand. The conjugated microporous polymer comprises an aromatic ring and/or a heterocyclic ring. The uranium complexing ligand is selected from the group consisting of a compound with a group containing phosphorus, a compound with a group containing nitrogen, and a compound with a group containing sulfur. The invention further provides use of the ligand-containing conjugated microporous polymer as a uranium adsorbent. The ligand-containing conjugated microporous polymer the invention is capable of adsorbing the radioactive element uranium in strongly acidic and strong-radiation environments.

  本发明涉及一种含配体的共轭微孔聚合物，它是通过共轭微孔聚合物和铀络合配体的共价偶联得到的。共轭微孔聚合物由芳香环和/或杂环组成。铀络合配体选自由含磷基团的化合物、含氮基团的化合物和含硫基团的化合物组成的组。本发明进一步提供了含配体共轭微孔聚合物作为铀吸附剂的用途。本发明的含配体共轭微孔聚合物能够在强酸性和强辐射环境中吸附放射性元素铀。
• Polyfluorenes with Phosphonate Groups in the Side Chains as Chemosensors and Electroluminescent Materials
  作者：Gang Zhou、Gang Qian、Liang Ma、Yanxiang Cheng、Zhiyuan Xie、Lixiang Wang、Xiabin Jing、Fosong Wang

  DOI：10.1021/ma050807h

  日期：2005.6.1

  Polyfluorenes (P1 and P2) with phosphonate groups in the side chains were designed and synthesized. Their absorption and photoluminescence spectra in solutions are solvent dependent and exhibit a red shift up to 14 and 6 nm, respectively, with increasing solvent polarity. The polymers are highly soluble in ethanol with a solution photoluminescence quantum yield of 0.74. Polymer P2 in thin film cast from ethanol shows high intrachain order as revealed by red-shifted absorption spectrum and emission spectrum along with well-resolved vibronic structure. Both P1 and P2 are highly sensitive and selective Fe3+ sensory materials, and the sensitivity is much higher than that of model compounds 3 and 4. The highest sensitivity was observed with polymer P1, and a 210-fold fluorescence quenching in dichloromethane was achieved. Polymer light-emitting diodes (PLEDs) were also fabricated to investigate the electroluminescent properties. A luminous efficiency of 1.49 cd/A with Commission Internationale de L'Eclairage (CIE) coordinates of (0.171, 0.131) at 100 cd/m(2) and a maximum brightness of 1750 cd/m(2) have been demonstrated.