10-(chloromethyl)-9-anthraldehyde | 1063984-90-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 10-(chloromethyl)-9-anthraldehyde
• 英文别名: 10-(Chloromethyl)anthracene-9-carbaldehyde
• CAS: 1063984-90-6
• 化学式: C₁₆H₁₁ClO
• 分子量: 254.716
• InChiKey: GXDWYLSVLGVHDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  10-(chloromethyl)-9-anthraldehyde 、 肌氨酸乙酯盐酸盐 在 potassium carbonate 作用下， 以 二氯甲烷 为溶剂， 以65%的产率得到[(10-formyl-anthracen-9-ylmethyl)-methyl-amino]-acetic acid ethyl ester
  参考文献：
  名称：

  Solid-bound, proton-driven, fluorescent ‘off–on–off’ switches based on PET (photoinduced electron transfer)

  摘要：

  Anthracene-based, H(+)-driven, 'off-on-off' fluorescent PET (photoinduced electron transfer) switches. are immobilized on organic and inorganic polymeric solids in the form of Tentagel(R) and silica, respectively. The environment of the organic bead displaces apparent switching thresholds towards lower pH Values whereas the Si-O(-) groups of silica electrostatically cause the opposite effect. These switches are ternary logic gate tags, one of which can be particularly useful in Strengthening molecular computational identification (MCID) of small solid objects. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.04.103
• 作为产物：
  描述：

  10-(hydroxymethyl)-9-anthraldehyde 在 氯化亚砜 作用下， 以 苯 为溶剂， 反应 2.0h， 生成 10-(chloromethyl)-9-anthraldehyde
  参考文献：
  名称：

  Solid-bound, proton-driven, fluorescent ‘off–on–off’ switches based on PET (photoinduced electron transfer)

  摘要：

  Anthracene-based, H(+)-driven, 'off-on-off' fluorescent PET (photoinduced electron transfer) switches. are immobilized on organic and inorganic polymeric solids in the form of Tentagel(R) and silica, respectively. The environment of the organic bead displaces apparent switching thresholds towards lower pH Values whereas the Si-O(-) groups of silica electrostatically cause the opposite effect. These switches are ternary logic gate tags, one of which can be particularly useful in Strengthening molecular computational identification (MCID) of small solid objects. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.04.103