imidazo[4,5-f]1,10-phenanthroline, ethanol solvate | 186298-53-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: imidazo[4,5-f]1,10-phenanthroline, ethanol solvate
• 英文别名: 2-phenylimidazo[4,5-f][1,10]phenanthroline ethanol solvate
• CAS: 186298-53-3
• 化学式: C₂H₆O*C₁₉H₁₂N₄
• 分子量: 342.4
• InChiKey: SCGDTJRTVKGPTI-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  水合三氯化钌 、 imidazo[4,5-f]1,10-phenanthroline, ethanol solvate 在 lithium chloride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以70.3%的产率得到cis-[Ru(2-phenylimidazo[4,5-f][1,10]phenanthroline)Cl2]*2H2O
  参考文献：
  名称：

  Syntheses, characterization and third-order nonlinear optical properties of ruthenium(II) complexes containing 2-phenylimidazo-[4,5-f][1,10]phenanthroline and extended diimine ligands

  摘要：

  Four novel ruthenium(II) complexes [RU(PIP)(2)L](2+) [PIP= 2-phenylimidazo-[4,5-f][1, 10]phenanthroline, L = 1, 10-phenanthroline (phen), 1,4,8,9-tetra-aza-triphenylene (tatp), dipyrido[3,2-a:2',3'-C]phenazine (dppz) and benzo[i]dipyrido[3,2-a:2',3'c]phenazine (dppn)] have been synthesized and characterized. The electrochemical behaviors of these complexes have been studied in acetonitrile by cyclic voltammetry. The nonlinear optical properties of the ruthenium(II) complexes were investigated by Z-scan techniques with 12 ns laser pulses at 540 nm, and all of them exhibit both NLO absorption and self-defocusing effect. The corresponding effective NLO susceptibility \chi (3)\ of the complexes is in the range of 4.78-8.49 x 10(-12) esu. The results indicate that the extension of the pi -framework of the ligands has an effect on the NLO properties of the complexes. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00813-0

文献信息

• Wu, Jian-Zhong; Ye, Bao-Hui; Wang, Lei, Journal of the Chemical Society, Dalton Transactions, 1997, # 8, p. 1395 - 1401
  作者：Wu, Jian-Zhong、Ye, Bao-Hui、Wang, Lei、Ji, Liang-Nian、Zhou, Jian-Ying、Li, Run-Hua、Zhou, Zhong-Yuan

  DOI：——

  日期：——