cis-[Pd(p-tolylsulfonyl dithiocarbamate)(1,2-bis(diphenylphosphino)ethane)] | 1261238-87-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-[Pd(p-tolylsulfonyl dithiocarbamate)(1,2-bis(diphenylphosphino)ethane)]
• 英文别名: cis-[Pd(p-MeC6H4SO2N=CS2)(dppe)]
• CAS: 1261238-87-2
• 化学式: C₃₄H₃₁NO₂P₂PdS₃
• 分子量: 750.191
• InChiKey: WPEUTGPZIOGELH-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  potassium tetrachloropalladate(II) 、 dipotassium p-tolylsulfonyl dithiocarbamate 、 1,2-双(二苯基膦)乙烷 以 甲醇 、 二氯甲烷 为溶剂， 生成 cis-[Pd(p-tolylsulfonyl dithiocarbamate)(1,2-bis(diphenylphosphino)ethane)]
  参考文献：
  名称：

  Syntheses, crystal structures and properties of sterically congested heteroleptic complexes of group 10 metal ions with p-tolylsulfonyl dithiocarbimate and 1,2-bis (diphenylphosphino) ethane

  摘要：

  Three novel heteroleptic complexes of the type cis- [ML(dppe)] [M = Ni(II), Pd(II), Pt(II); L = p-tolylsulfonyl dithiocarbimate; dppe = 1,2-bis(diphenylphosphino)ethane] have been prepared and characterized. X-ray crystallography revealed the close proximity of one of the ortho phenyl protons of the dppe ligand to the metal in the Ni(II) complex showing existence of the less common C-H center dot center dot center dot Ni anagostic interactions observed for the first time in the dithio-phosphine mixed-ligand systems. The platinum complex showed a strong photoluminescence emission near visible region in CH2Cl2 solution. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.08.014