[Mn(N,N'-bis((pyridin-2-yl)benzylidene)ethane-1,2-diamine)(thiocyanato)2] | 1286710-64-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: [Mn(N,N'-bis((pyridin-2-yl)benzylidene)ethane-1,2-diamine)(thiocyanato)2]
• CAS: 1286710-64-2
• 化学式: C₂₈H₂₂MnN₆S₂
• 分子量: 561.593
• InChiKey: FFBILCGARVHSQG-WLOGLECFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  硫氰酸铵 、 manganese(II) chloride tetrahydrate 、 N,N’-(ethane-1,2-diyl)bis(1-phenyl-1-(pyridin-2-yl)methanimine) 以 甲醇 为溶剂， 以57%的产率得到[Mn(N,N'-bis((pyridin-2-yl)benzylidene)ethane-1,2-diamine)(thiocyanato)2]
  参考文献：
  名称：

  Synthesis, crystal structure and antibacterial activity of a group of mononuclear manganese(II) Schiff base complexes

  摘要：

  Five mononuclear complexes of manganese(II) of a group of the general formula. [MnL(NCS)(2)] where the Schiff base L = N,N'-bis[(pyridin-2-yl)ethylidene]ethane-1,2-diamine (L-1), (1); N,N'-bis[(pyridin-2-yl)benzylidene]ethane-1,2-diamine (L-2), (2); N,N'-bis[(pyridin-2-yl)methylidene]propane-1,2-diamine (L-3), (3); N,N'-bis[(pyridin-2-yl)ethylidene]propane-1,2-diamine (L-4), (4) and N,N'-bis[(pyridin-2-yl)benzylidene]propane-1,2-diamine (L-5). (5) have been prepared. The syntheses have been achieved by reacting manganese chloride with the corresponding tetradentate Schiff bases in presence of thiocyanate in the molar ratio of 1:1:2. The complexes have been characterized by IR spectroscopy, elemental analysis and other physicochemical studies, including crystal structure determination of 1, 2 and 4. Structural studies reveal that the complexes 1, 2 and 4 adopt highly distorted octahedral geometry. The antibacterial activity of all the complexes and their respective Schiff bases has been tested against Gram(+) and Gram(-) bacteria. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.12.012