cerium(III)(2,6-bis[2-formylphenoxymethyl]pyridine)2 nitrate dihydrate | 165285-17-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: cerium(III)(2,6-bis[2-formylphenoxymethyl]pyridine)2 nitrate dihydrate
• 英文别名: [Ce(2,6-bis(2-formylphenoxymethyl)pyridine)2(nitrate)3(water)2]；cerium(3+);2-[[6-[(2-formylphenoxy)methyl]pyridin-2-yl]methoxy]benzaldehyde;trinitrate;dihydrate
• CAS: 165285-17-6
• 化学式: C₄₂H₃₈CeN₅O₁₉
• 分子量: 1056.91
• InChiKey: YVMNEVYZXWQBQJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cerous nitrate 、 3,14,25-Trioxa-11,17,31-triazatetracyclo[25.3.1.04,9.019,24]hentriaconta-1(31),4,6,8,10,17,19,21,23,27,29-undecaene 以 甲醇 为溶剂， 以19%的产率得到cerium(III)(2,6-bis[2-formylphenoxymethyl]pyridine)2 nitrate dihydrate
  参考文献：
  名称：

  2,6-双[2-甲酰基苯氧基甲基]吡啶铈（III）配合物的合成和晶体结构

  摘要：

  摘要报道了2,6-双[2-甲酰基苯氧基甲基]-吡啶的十配位硝酸铈（III）配合物的合成及X射线晶体结构。

  DOI：

  10.1016/0020-1693(94)04371-2

文献信息

• Synthesis, crystal structures and luminescent properties of an isotypic series of rare-earths complexes with a dialdehyde ligand
  作者：Sara Luisa Rodríguez De Luna、Luis Ángel Garza、Sylvain Bernès、Perla Elizondo、Blanca Nájera、Nancy Pérez

  DOI：10.1016/j.poly.2010.03.018

  日期：2010.6

  A series of mononuclear complexes based on lanthanide ions has been synthesized and X-ray characterized. The compounds [Ln(III)L(2)(NO(3))(3)(H(2)O)(2)] (Ln = La, Ce, Pr, Nd, Sm, Gd and Tm; L = 2,6-bis(2-formylphenoxymethyl)pyridine) are found to be isomorphous and isostructural. Ligand L systematically coordinates through one carbonyl functionality, and the resulting complexes are placed on a twofold axis in crystals belonging to C2/c space-group. Emission spectra for Ln = La, Pr, Nd revealed a correlation between the Ln-O coordination bond length and the photoluminescent properties of the complexes, in line with a Forster-Dexter mechanism for intramolecular energy transfer. Ligand L is therefore a suitable sensitizer for lanthanide ions. (C) 2010 Elsevier Ltd. All rights reserved.