2.5-bis(5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl)phenol | 867380-76-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2.5-bis(5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl)phenol
• 英文别名: 2,5-Bis(5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl)phenol；2,5-bis[5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl]phenol
• CAS: 867380-76-5
• 化学式: C₃₀H₃₀N₄O₃
• 分子量: 494.593
• InChiKey: MEMUUQIOBJIXGM-UHFFFAOYSA-N

物化性质

• 沸点：
  644.1±65.0 °C(Predicted)
• 密度：
  1.175±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  37
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  98.1
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  5-(4-bromobutyl)-bicyclo[2.2.1]hept-2-ene 、 2.5-bis(5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl)phenol 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 15.0h， 以58%的产率得到5,5'-(2-(4-(bicyclo[2.2.1]hept-5-en-2-yl)butoxy)-1,4-phenylene)bis(2-(4-tert-butylphenyl)-1,3,4-oxadiazole)
  参考文献：
  名称：

  [EN] ROMP-POLYMERIZABLE ELECTRON TRANSPORT MATERIALS BASED ON A BIS-OXADIAZOLE MOIETY
  [FR] MATIÈRES DE TRANSPORT D'ÉLECTRONS POLYMÉRISABLES PAR OUVERTURE DE CYCLE PAR MÉTATHÈSE(ROMP) À BASE D'UNE FRACTION BIS-OXADIAZOLE

  摘要：

  这项发明涉及一种可溶解的去甲基环戊烯单体、聚（去甲基环戊烯）均聚物和含有功能化双-噁二唑侧链的聚（去甲基环戊烯）共聚物化合物，以及电子注入/传输层、阻挡孔层或发光材料、有机电子器件和包括这些化合物的组合物。

  公开号：

  WO2009080797A1
• 作为产物：
  描述：

  5,5'-(2-methoxy-1,4-phenylene)bis(2-(4-tert-butylphenyl)-1,3,4-oxadiazole) 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 以92%的产率得到2.5-bis(5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl)phenol
  参考文献：
  名称：

  [EN] ROMP-POLYMERIZABLE ELECTRON TRANSPORT MATERIALS BASED ON A BIS-OXADIAZOLE MOIETY
  [FR] MATIÈRES DE TRANSPORT D'ÉLECTRONS POLYMÉRISABLES PAR OUVERTURE DE CYCLE PAR MÉTATHÈSE(ROMP) À BASE D'UNE FRACTION BIS-OXADIAZOLE

  摘要：

  这项发明涉及一种可溶解的去甲基环戊烯单体、聚（去甲基环戊烯）均聚物和含有功能化双-噁二唑侧链的聚（去甲基环戊烯）共聚物化合物，以及电子注入/传输层、阻挡孔层或发光材料、有机电子器件和包括这些化合物的组合物。

  公开号：

  WO2009080797A1

文献信息

• Romp-Polymerizable Electron Transport Materials Based On A Bis-Oxadiazole Moiety
  申请人：Marder Seth

  公开号：US20110009584A1

  公开（公告）日：2011-01-13

  This invention relates generally to a solution processable norbornene monomer, poly(norbornene) homopolymer, and poly(norbornene) copolymer compounds containing a functionalized bis-oxadiazole side chain, and to an electron injecting/transporting layer, a hole-blocking layer, or an emissive material, organic electronic devices and compositions which include these compounds.

  本发明涉及一种可溶解的诺博烯单体、聚诺博烯同聚物和含有功能化双噁唑侧链的聚诺博烯共聚物化合物，以及用于电子注入/传输层、阻挡孔层或发射材料的有机电子器件和组合物，这些化合物包括在内。
• ROMP-POLYMERIZABLE ELECTRON TRANSPORT MATERIALS BASED ON A BIS-OXADIAZOLE MOIETY
  申请人：Georgia Tech Research Corporation

  公开号：EP2234991A1

  公开（公告）日：2010-10-06
• ORGANIC OPTOELECTRONIC APPARATUS
  申请人：OSRAM OLED GmbH

  公开号：US20170125695A1

  公开（公告）日：2017-05-04

  The invention relates to an organic optoelectronic apparatus comprising: a first electrode ( 2 ), a radiation-emitting region ( 4 ) arranged between the first and second electrodes, and a second electrode ( 9 ), wherein the first and second electrodes can inject charge carriers of different polarity into the radiation-emitting region, wherein the radiation-emitting region ( 4 ) has a dual emitter and a further emitter, wherein the further emitter is transferred by the charge carrier into an electronically excited state and, on the transition into the basic electronic state from this electronically excited state, emits radiation, and wherein the dual emitter has a first electronically excited state and a second electronically excited state, which can be reached from the first electronically excited state by intramolecular proton transfer or intramolecular charge transfer, and the dual emitter has an emission starting from the second electronically excited state into a second basic state. The radiation emitted by this apparatus has an improved CRI value owing to the simultaneous use of a dual emitter and a further emitter.
• Optoelectronic Device, Use of a Dual Emitter as Wavelength Conversion Material
  申请人：OSRAM OLED GmbH

  公开号：US20170324007A1

  公开（公告）日：2017-11-09

  An optoelectronic apparatus is disclosed. In an embodiment, the apparatus includes at least one wavelength conversion region which includes at least one dual emitter as wavelength conversion material, wherein the wavelength conversion region converts primary radiation at least in part into secondary radiation, and wherein the dual emitter includes a first electronic base state and a second electronic base state, together with a first electronically excited state and a second electronically excited state which may be reached from the first electronically excited state. The dual emitter further includes emission proceeding from the second electronically excited state into the second base state.
• US9954147B2
  申请人：——

  公开号：US9954147B2

  公开（公告）日：2018-04-24