[4-(4-tert-butylphenoxy)phenyl]-[4-(4-hydroxyphenoxy)phenyl]methanone | 917868-97-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [4-(4-tert-butylphenoxy)phenyl]-[4-(4-hydroxyphenoxy)phenyl]methanone
• CAS: 917868-97-4
• 化学式: C₂₉H₂₆O₄
• 分子量: 438.523
• InChiKey: XYOWRSVIGRPWOF-UHFFFAOYSA-N

物化性质

• 沸点：
  585.0±50.0 °C(Predicted)
• 密度：
  1.172±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.51
• 重原子数：
  33.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  55.76
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  (4-氟苯基)-[4-(4-甲氧基苯氧基)苯基]甲酮 、 [4-(4-tert-butylphenoxy)phenyl]-[4-(4-hydroxyphenoxy)phenyl]methanone 在 potassium carbonate 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 4.0h， 以93%的产率得到[4-(4-tert-butylphenoxy)phenyl]-[4-[4-[4-[4-(4-methoxyphenoxy)benzoyl]phenoxy]phenoxy]phenyl]methanone
  参考文献：
  名称：

  Self-Assembled Lamellar Nanostructures of Wholly Aromatic Rod−Rod-Type Block Molecules

  摘要：

  Wholly aromatic rod-rod type di- and triblock molecules, oligo(ether sulfone)-b-oligo(ether ketone)s (OES-OEK), were synthesized to study a solid-state self-assembled nanostructure. The OES and OEK segments in the block molecules form segregated crystalline domains. The energy-filtering transmission electron microscopy images revealed that the di- and triblock OES-OEK co-oligomers formed lamellar nanostructures with a periodicity of similar to 9 and 13 nm, respectively.

  DOI：

  10.1021/ol061929c
• 作为产物：
  描述：

  (4-氟苯基)-[4-(4-甲氧基苯氧基)苯基]甲酮 在 三溴化硼 、 potassium carbonate 作用下， 以 二氯甲烷 、 N,N-二甲基乙酰胺 为溶剂， 反应 9.0h， 生成 [4-(4-tert-butylphenoxy)phenyl]-[4-(4-hydroxyphenoxy)phenyl]methanone
  参考文献：
  名称：

  Self-Assembled Lamellar Nanostructures of Wholly Aromatic Rod−Rod-Type Block Molecules

  摘要：

  Wholly aromatic rod-rod type di- and triblock molecules, oligo(ether sulfone)-b-oligo(ether ketone)s (OES-OEK), were synthesized to study a solid-state self-assembled nanostructure. The OES and OEK segments in the block molecules form segregated crystalline domains. The energy-filtering transmission electron microscopy images revealed that the di- and triblock OES-OEK co-oligomers formed lamellar nanostructures with a periodicity of similar to 9 and 13 nm, respectively.

  DOI：

  10.1021/ol061929c

文献信息

• Self-Assembled Lamellar Nanostructures of Wholly Aromatic Rod−Rod-Type Block Molecules
  作者：Teruaki Hayakawa、Raita Goseki、Masa-aki Kakimoto、Masatoshi Tokita、Junji Watanabe、Yonngui Liao、Shin Horiuchi

  DOI：10.1021/ol061929c

  日期：2006.11.1

  Wholly aromatic rod-rod type di- and triblock molecules, oligo(ether sulfone)-b-oligo(ether ketone)s (OES-OEK), were synthesized to study a solid-state self-assembled nanostructure. The OES and OEK segments in the block molecules form segregated crystalline domains. The energy-filtering transmission electron microscopy images revealed that the di- and triblock OES-OEK co-oligomers formed lamellar nanostructures with a periodicity of similar to 9 and 13 nm, respectively.