| 39733-15-8

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• CAS: 39733-15-8
• 化学式: CuH₁₂N₄*O₈S₂
• 分子量: 323.795
• InChiKey: BBXIIMFVNCYUFQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 氨
  参考文献：
  名称：

  Barbieri, G. A.; Calzolari, F., Zeitschrift fur anorganische Chemie, 1911, vol. 71, p. 347 - 355

  摘要：

  DOI：
• 作为产物：
  描述：

  ammonium persulfate 、 氨 、 copper(II) sulfate 以 氨 为溶剂， 生成
  参考文献：
  名称：

  Barbieri, G. A.; Calzolari, F., Zeitschrift fur anorganische Chemie, 1911, vol. 71, p. 347 - 355

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B1, 260, page 589 - 591
  作者：

  DOI：——

  日期：——
• Synthesis, vibrational spectra, and structure of divalent metal peroxodisulfates
  作者：L. S. Skogareva、N. A. Minaeva、T. V. Filippova

  DOI：10.1134/s0036023609090010

  日期：2009.9

  Simple strontium peroxodisulfate SrS2O8 center dot 4H(2)O was synthesized by the reaction of solid Sr(OH)(2) center dot 8H(2)O taken in 30% excess with an aqueous solution of (NH4)(2)S2O8; simple magnesium peroxodisulfate MgS2O8 center dot 6H(2)O was synthesized by the reaction of an aqueous solution of BaS2O8 with a stoichiometric amount of MgSO4 center dot 7H(2)O. Persulfate ammine complexes [M(NH3)(4)]S2O8 (M = Zn, Cu) were prepared in concentrated aqueous ammonia from [Zn(NH3)(4)](OH)(2), [Cu(NH3)(4)](OH)(2), and an ammoniac solution of (NH4)(2)S2O8. The compounds were characterized by X-ray powder diffraction (pRSA) and vibrational (IR and Raman) spectroscopy. Their stability was studied during storage and in DTA experiments. The [Zn(NH3)(4)]S2O8 structure was solved. Its crystals are orthorhombic, a = 10.5512(8) , b = 12.8039(12) , c = 8.0448(5) , V = 1086(15) (3), Z = 4, space group Pna2(1). The compound is built of [Zn(NH3)(4)](2+) complex cations and S2O (8) (2-) persulfate anions. In a cation, Zn-N bond lengths are within 2.04(2)-2.056(14) . In an anion, the lengths of S(1)-O(4), S(2)-O(5), and O(4)-O(5) bridging bonds are, respectively, 1.676(14), 1.672(16), and 1.465(16) ; the other S-O bond lengths are within 1.409(14)-1.443(12) ; the S(1)O(4)O(5)S(2) torsion angle is 140.8(7)A degrees.