| 1268033-84-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 1268033-84-6
• 化学式: C₁₃H₁₂N₃O₃Zn*NO₃
• 分子量: 385.651
• InChiKey: UIJSKTBNOGQBIU-SFRYUHGMSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 zinc(II) oxide
  参考文献：
  名称：

  Solution and solid-state studies of complexation of transition-metal cations and Al(III) by aroylhydrazones derived from nicotinic acid hydrazide

  摘要：

  Reactions of first series transition-metal cations, Cd(II) and Al(III) with two aroylhydrazones derived from nicotinic acid hydrazide and salicylaldehyde or o-vanillin were studied at 25 degrees C in buffered dioxane/water 1/1 mixture (pH 5.8) by means of spectrophotometric and spectrofluorimetric titrations. The addition of Mn(II) or Cd(II) ions in hydrazone solutions had no effect on their absorption spectra whereas the addition of Ni(II) and Cr(III) immediately caused precipitation. The reaction of Zn(II) with salicylaldehyde derivative was found to be photosensitive. Relatively high conditional stability constants of 1:1 complexes of Cu(II), Zn(II) and Al(III) with both ligands were determined. Solid complexes of Cu(II), Ni(II) and Zn(II) with aroylhydrazones studied were isolated and characterized by elemental and thermogravimetric analyses, magnetic susceptibility measurements (in the case of Cu(II) and Ni(II)) and IR spectrometry. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.10.017
• 作为产物：
  描述：

  zinc(II) nitrate hexahydrate 、 N′-(2-hydroxybenzylidene)nicotinohydrazide 、 水 以 甲醇 为溶剂， 以31%的产率得到
  参考文献：
  名称：

  Solution and solid-state studies of complexation of transition-metal cations and Al(III) by aroylhydrazones derived from nicotinic acid hydrazide

  摘要：

  Reactions of first series transition-metal cations, Cd(II) and Al(III) with two aroylhydrazones derived from nicotinic acid hydrazide and salicylaldehyde or o-vanillin were studied at 25 degrees C in buffered dioxane/water 1/1 mixture (pH 5.8) by means of spectrophotometric and spectrofluorimetric titrations. The addition of Mn(II) or Cd(II) ions in hydrazone solutions had no effect on their absorption spectra whereas the addition of Ni(II) and Cr(III) immediately caused precipitation. The reaction of Zn(II) with salicylaldehyde derivative was found to be photosensitive. Relatively high conditional stability constants of 1:1 complexes of Cu(II), Zn(II) and Al(III) with both ligands were determined. Solid complexes of Cu(II), Ni(II) and Zn(II) with aroylhydrazones studied were isolated and characterized by elemental and thermogravimetric analyses, magnetic susceptibility measurements (in the case of Cu(II) and Ni(II)) and IR spectrometry. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.10.017