| 1358031-67-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1358031-67-0
• 化学式: C₄H₈O*C₇H₈*C₄₁H₆₆Br₂Mg₂O₅
• 分子量: 1011.64
• InChiKey: FPQAWTIKYMGNEL-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 抗氧剂 702 、 甲苯 在 magnesium,1,3,5-trimethylbenzene-6-ide,bromide 作用下， 反应 12.0h， 生成
  参考文献：
  名称：

  Synthesis and characterization of 4,4′-methylenebis (2,6-di-tert-butylphenol) derivatives of a series of metal alkoxides and alkyls

  摘要：

  Investigation of the coordination behavior of 4,4'-methylenebis(2,6-di-tert-butylphenol) (or H-2-4DBP) with a series of metal alkoxides led to isolation of [(OR)(3)M](2)(mu-4DBP), where M/OR Ti/OBut (2), Ti/ONep (3), Zr/OBut (4), Hf/OBut (5), and [(py)(OR)(3)M](2)(mu-4DBP)center dot py (5a), where py = pyridine and ONep = OCH2C(CH3)(3). Metal alkyl derivatives of 4DBP were also studied and found to form similar di-substituted species: [(py)(2)(Et)Zn](2)(mu-4DBP)center dot py (6), [(THF)(3)(Br)Mg](2)(mu-4DBP) (7), [(THF)(2)(Br) Mg](mu-4DBP)[Mg(Br)(THF)(3)]center dot(THF, tol) (7a), and [(py)(R)(2)Al](2)(mu-4DBP), where R = CH3 (8), Et (9), CH2CH(CH3)(2) (10); tol = toluene and THF tetrahydrofuran. All structures demonstrate the bridging nature of 4DBP and the ability to bind a variety of metal centers. Solution state NMR indicates that the structures of 2-10 are retained in solution. Thermal analyses indicate that 4DBP is preferentially lost during heating.

  DOI：

  10.1080/00958972.2012.654785