[Cd(salicylidene-DL-alanine(-2H))(thiophene-o-carboxaldene-p-toluidine)(H2O)] | 927189-80-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [Cd(salicylidene-DL-alanine(-2H))(thiophene-o-carboxaldene-p-toluidine)(H2O)]
• CAS: 927189-80-8
• 化学式: C₂₂H₂₂CdN₂O₄S
• 分子量: 522.904
• InChiKey: ORXOTJPSUJQVDT-JREDVJKQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-methyl-N-(thiophen-2-ylmethylene)aniline 、 cadmium(II) nitrate tetrhydrate 、 水 、 potassium(salicylidene-DL-alanine(-H)) 以 甲醇 、 水 为溶剂， 以49%的产率得到[Cd(salicylidene-DL-alanine(-2H))(thiophene-o-carboxaldene-p-toluidine)(H2O)]
  参考文献：
  名称：

  Preparation of Schiff’s base complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Cd(II) and their spectroscopic, magnetic, thermal, and antifungal studies

  摘要：

  The potassium salt of salicylidene-DL-alanine (KHL), bis(benzylidene)ethylenediamine (A), thiophene-o-carboxaldene-p-toluidine (A(2)), and its metal complexes of the formula [(M-II(L)(A)(H2O)] (M = Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Cd(II); A = A(1) or A(2)) are prepared. They are characterized by elemental analysis, magnetic susceptibility measurements, thermogravimetric analysis, and infrared and electronic spectral studies. The electronic spectral and magnetic moment data suggest an octahedral geometry for the complexes. All of these complexes, metal nitrates, fungicides (bavistin and emcarb), and ligands are screened for their antifungal activity against Aspergillus niger, Fusarium oxysporum, and Aspergillus flavus C, using a plate poison technique. The complexes show higher activity than those of the free ligands, metal nitrate, and the control (DMSO) and moderate activity against bavistin and emcarb.

  DOI：

  10.1134/s1070328406060066