Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(E)-(S)-5-hydroxy-1,5-dimethyl-1-((S)-4-methyl-cyclohex-3-enyl)-hex-3-enyloxy]-6-methyl-tetrahydro-pyran-3-yl ester | 126582-69-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(E)-(S)-5-hydroxy-1,5-dimethyl-1-((S)-4-methyl-cyclohex-3-enyl)-hex-3-enyloxy]-6-methyl-tetrahydro-pyran-3-yl ester
• CAS: 126582-69-2
• 化学式: C₂₇H₄₂O₉
• 分子量: 510.625
• InChiKey: BJPFENKPVSGNJH-UNEZZANUSA-N

反应信息

• 作为产物：
  描述：

  Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(S)-1,5-dimethyl-1-((S)-4-methyl-cyclohex-3-enyl)-hex-4-enyloxy]-6-methyl-tetrahydro-pyran-3-yl ester 在 4,5,6,7-tetrachloro-2',4',5',7'-tetraiodofluorescein disodium salt 二甲基硫 、 氧气 作用下， 生成 Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(E)-(S)-5-hydroxy-1,5-dimethyl-1-((S)-4-methyl-cyclohex-3-enyl)-hex-3-enyloxy]-6-methyl-tetrahydro-pyran-3-yl ester 、 Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-[(S)-4-hydroxy-1,5-dimethyl-1-((S)-4-methyl-cyclohex-3-enyl)-hex-5-enyloxy]-6-methyl-tetrahydro-pyran-3-yl ester
  参考文献：
  名称：

  来自红花的红没药烷相关糖苷

  摘要：

  摘要 从红花正己烷提取物的极性部分分离得到两种新的倍半萜苷。它们被鉴定为红没药烷和三-或 - 红没药烷岩藻糖苷，它们的结构通过从 (-)-α-红没药醇-β-d-岩藻糖苷合成得到证实。

  DOI：

  10.1016/0031-9422(90)85135-3