| 1356036-42-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 1356036-42-4
• 化学式: C₄₄H₃₅CuN₄O₂
• 分子量: 715.333
• InChiKey: SMHMPWYJIMSRCQ-SDNGJSABSA-M

反应信息

• 作为产物：
  描述：

  在 盐酸羟胺 、 三乙胺 、 苯酐 作用下， 以 乙腈 为溶剂， 反应 0.5h， 以80%的产率得到
  参考文献：
  名称：

  Synthesis, electrochemical and photophysical properties of β-carboxy triaryl corroles

  摘要：

  An unswerving one-pot conversion of 3-formyl-5,10,15-triaryl substituted corroles and their copper(III) derivatives to the corresponding 3-carboxy-5,10,15-triaryl substituted corroles was achieved by adopting mild reaction conditions by using hydroxylamine hydrochloride and phthalic anhydride. All these substituted carboxy corroles were completely characterized by using Mass, CHN analysis, IR, H-1 NMR, UV-vis., Fluorescence spectroscopies and cyclic voltammetry. Both the absorption maxima and emission maxima of carboxy corroles were red shifted by 5-13 nm. The LUMO level of these corroles is above the TiO2 conduction band and HOMO level was below the redox electrolytes. These beta-carboxy corroles confined with may find applications as sensitizers in dye-sensitized solar cells. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.12.068