[Cd(4,5-diazafluoren-9-one)2(triphenylphosphine oxide)(acetate)]ClO4 | 604757-00-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cd(4,5-diazafluoren-9-one)2(triphenylphosphine oxide)(acetate)]ClO4
• CAS: 604757-00-8
• 化学式: C₄₂H₃₀CdN₄O₅P*ClO₄
• 分子量: 913.558
• InChiKey: JVHHAZSXYVODIA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  溶剂黄146 、 三苯基膦 、 cadmium(II) acetate dihydrate 、 sodium perchlorate 、 4,5-二氮芴-9-酮 在 air 作用下， 以 乙醇 为溶剂， 以60%的产率得到[Cd(4,5-diazafluoren-9-one)2(triphenylphosphine oxide)(acetate)]ClO4
  参考文献：
  名称：

  Complex [Cd(dafo)2(tphpo)(CH3COO)]ClO4 (dafo=4,5-diazafluoren-9-one, tphpo=triphenylphosphine oxide) with chiral metal centers. Helical packing induced by π–π stacking interactions of dafo rings

  摘要：

  The first complex of 4,5-diazafluoren-9-one (dafo) and cadmium: [Cd(dafo)(2)(tphpo)(CH3COO)]ClO4 (triphenylphosphine oxide = tphpo) is a quaternary complex with chiral metal centers and crystallizes in a monoclinic cell with space group P-2(1)/n. Cadmium centers with 7-fold coordination adopt a distorted monocapped trigonal prismatic geometry. Two oxygen atoms of acetate and one oxygen atom of triphenylphosphine oxide form the top triangle of the trigonal prism, while three nitrogen atoms from two dafo groups construct the bigger bottom triangle. The last nitrogen atom of dafo groups occupies the monocapped position. Here, dafo molecules display two different coordination patterns, namely unsymmetric and symmetric chelation. Moreover, the interesting linking of screw related cations is fabricated by inter-molecular pi-pi stacking interactions in the complex. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(03)00325-9