cis-1,3,3-trichloro-1-fluoro-propene | 1281987-78-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: cis-1,3,3-trichloro-1-fluoro-propene
• 英文别名: 1-Fluoro-1,3,3-trichloroprop-1-ene；(Z)-1,3,3-trichloro-1-fluoroprop-1-ene
• CAS: 1281987-78-7
• 化学式: C₃H₂Cl₃F
• 分子量: 163.406
• InChiKey: YYDPDTHRBQYLSK-HNQUOIGGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  7
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Method for Producing Trans-1-Chloro-3,3,3-Trifluoropropene
  申请人：Central Glass Company, Limited

  公开号：US20190031583A1

  公开（公告）日：2019-01-31

  The present invention provides a method for efficiently producing 1-chloro-3,3,3-trifluoropropene from a low-reactivity intermediate product. More specifically, provided is a method for producing trans-1-chloro-3,3,3-trifluoropropene, characterized by reacting a halogenated C 3 hydrocarbon compound represented by the following general formula (1) with hydrogen fluoride in a gas phase in the presence of a solid catalyst and chlorine C 3 H X Cl Y F Z (1) wherein X is 2 or 3; when X=2, Y is an integer of 1 to 4, Z is an integer of 0 to 3, and Y+Z=4; and, when X=3, Y is an integer of 1 to 5, Z is an integer of 0 to 4, and Y+Z=5; provided that the general formula (1) represents any halogenated C 3 hydrocarbon compound other than trans-1-chloro-3,3,3-trifluoropropene.

  本发明提供了一种从低反应性中间产物高效生产1-氯-3,3,3-三氟丙烯的方法。更具体地，提供了一种生产反-1-氯-3,3,3-三氟丙烯的方法，其特征在于，在固体催化剂和氯气存在下，在气相中将以下通式（1）表示的卤代C3烃化合物与氢氟酸反应。 C3HXClYFZ(1) 其中，X为2或3；当X=2时，Y为1至4的整数，Z为0至3的整数，且Y+Z=4；当X=3时，Y为1至5的整数，Z为0至4的整数，且Y+Z=5；前提是通式（1）表示除反-1-氯-3,3,3-三氟丙烯以外的任何卤代C3烃化合物。
• METHOD FOR PRODUCING TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE
  申请人：Central Glass Company, Limited

  公开号：US20170113986A1

  公开（公告）日：2017-04-27

  A method for producing 1-chloro-3,3,3-trifluoropropene efficiently from an intermediate product having a low reactivity is provided. A method for producing trans-1-chloro-3,3,3-trifluoropropene comprising reacting a halogenated hydrocarbon compound having 3 carbon atoms represented by Formula (1) shown below in a gas phase with hydrogen fluoride in the presence of chlorine is provided. C 3 H X Cl Y F Z (1) wherein X is 2 or 3; and when X=2, Y is an integer from 1 to 4, Z is an integer from 0 to 3, and Y+Z=4; and when X=3, Y is an integer from 1 to 5, Z is an integer from 0 to 4, and Y+Z=5; provided that Formula (1) shown above represents a halogenated hydrocarbon compound having 3 carbon atoms excluding trans-1-chloro-3,3,3-trifluoropropene.

  提供了一种高效从反应活性低的中间产物中生产1-氯-3,3,3-三氟丙烯的方法。提供了一种生产反式-1-氯-3,3,3-三氟丙烯的方法，包括在气相中在氯的存在下将下式所示的具有3个碳原子的卤代烃化合物与氟化氢反应。 C3HXClYFZ（1），其中X为2或3；当X=2时，Y为1至4的整数，Z为0至3的整数，且Y+Z=4；当X=3时，Y为1至5的整数，Z为0至4的整数，且Y+Z=5；前提是上述公式（1）表示具有3个碳原子的卤代烃化合物，不包括反式-1-氯-3,3,3-三氟丙烯。
• METHOD FOR PRODUCING TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPANE
  申请人：Central Glass Company, Limited

  公开号：EP3170803A1

  公开（公告）日：2017-05-24

  Provided is a method for producing trans-1-chloro-3,3,3-trifluoropropane efficiently from an intermediate product having a low reactivity. Provided is a method for producing trans-1-chloro-3,3,3-trifluoropropane characterized by reacting a halogenated hydrocarbon compound having three carbon atoms represented by general formula (1) in a gas phase with hydrogen fluoride in the presence of chlorine. General formula (1): C3HXClYFZ (In the formula: X is 2 or 3; and when X=2, Y is an integer from 1 to 4, Z is an integer from 0 to 3, and Y+Z=4; and when X=3, Y is an integer from 1-5, Z is an integer from 0-4, Y+Z=5. General formula (1) indicates a halogenated hydrocarbon compound having 3 carbon atoms and excluding trans-1-chloro-3,3,3-trifluoropropane.).

  本发明提供了一种从反应活性低的中间产物高效生产反式-1-氯-3,3,3-三氟丙烷的方法。本发明提供了一种生产反式-1-氯-3,3,3-三氟丙烷的方法，其特征在于在气相中使通式（1）表示的具有三个碳原子的卤代烃化合物与氟化氢在氯的存在下反应。通式(1)C3HXClYFZ （在式中：X 为 2 或 3；当 X=2 时，Y 为 1 至 4 的整数，Z 为 0 至 3 的整数，Y+Z=4；当 X=3 时，Y 为 1 至 5 的整数，Z 为 0 至 4 的整数，Y+Z=5。通式（1）表示具有 3 个碳原子的卤代烃化合物，不包括反式-1-氯-3,3,3-三氟丙烷）。
• Azeotropic compositions of hydrogen fluoride and Z-3,3,3-trifluoro-1-chloropropene
  申请人：ARKEMA FRANCE

  公开号：US10029961B2

  公开（公告）日：2018-07-24

  An azeotropic or quasi-azeotropic composition including hydrogen fluoride, Z-3,3,3-trifluoro-1-chloropropene and one or more (hydro)halocarbon compounds including 1 to 3 carbon atoms. The (hydro) halocarbon compounds are preferably selected among tetrachlorofluoropropanes, trichlorodifluoropropanes, dichlorotrifluoropropanes, chlorotetrafluoropropanes, pentafluoropropanes, dichlorodifluoropropenes, chlorotrifluoropropenes and tetrafluoropropenes. A process for producing a main (hydro)halocarbon compound, including the formation of a mixture of compounds including hydrogen fluoride, Z-3,3,3-trifluoro-1-chloropropene and one or more other (hydro)halocarbon compounds, distillation of this mixture making it possible to collect, firstly, an azeotropic composition, and, secondly, at least one of the compounds of the mixture.

  一种共沸或准共沸物，包括氟化氢、Z-3,3,3-三氟-1-氯丙烯和一种或多种含 1 至 3 个碳原子的（氢）卤化合物。(氢)卤烃化合物最好选自四氟丙烷、三氯二氟丙烷、二氯三氟丙烷、氯四氟丙烷、五氟丙烷、二氯二氟丙烯、氯三氟丙烯和四氟丙烯。一种生产主要（氢）卤化合物的工艺，包括形成包括氟化氢、Z-3,3,3-三氟-1-氯丙烯和一种或多种其他（氢）卤化合物在内的混合物，蒸馏该混合物，首先收集共沸物，其次收集混合物中的至少一种化合物。
• Method for producing trans-1-chloro-3,3,3-trifluoropropene
  申请人：Central Glass Company, Limited

  公开号：US10519083B2

  公开（公告）日：2019-12-31

  The present invention provides a method for efficiently producing 1-chloro-3,3,3-trifluoropropene from a low-reactivity intermediate product. More specifically, provided is a method for producing trans-1-chloro-3,3,3-trifluoropropene, characterized by reacting a halogenated C3 hydrocarbon compound represented by the following general formula (1) with hydrogen fluoride in a gas phase in the presence of a solid catalyst and chlorine C3HXClYFZ  (1) wherein X is 2 or 3; when X=2, Y is an integer of 1 to 4, Z is an integer of 0 to 3, and Y+Z=4; and, when X=3, Y is an integer of 1 to 5, Z is an integer of 0 to 4, and Y+Z=5; provided that the general formula (1) represents any halogenated C3 hydrocarbon compound other than trans-1-chloro-3,3,3-trifluoropropene.

  本发明提供了一种从低反应性中间产物高效生产 1-氯-3,3,3-三氟丙烯的方法。更具体地说，本发明提供了一种生产反式-1-氯-3,3,3-三氟丙烯的方法，其特征在于：在固体催化剂和氯的存在下，由下通式（1）代表的卤代 C3 烃化合物与氟化氢在气相中发生反应 C3HXClYFZ (1) 其中，X 为 2 或 3；当 X=2 时，Y 为 1 至 4 的整数，Z 为 0 至 3 的整数，且 Y+Z=4 ；以及，当 X=3 时，Y 为 1 至 5 的整数，Z 为 0 至 4 的整数，且 Y+Z=5；条件是通式（1）代表反式-1-氯-3,3,3-三氟丙烯以外的任何卤代 C3 烃化合物。