[Os(C(COOMe)=CHCOOMe)(P(OEt)2Ph)4]BPh4 | 164856-99-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Os(C(COOMe)=CHCOOMe)(P(OEt)2Ph)4]BPh4
• CAS: 164856-99-9
• 化学式: C₂₄H₂₀B*C₄₆H₆₇O₁₂OsP₄
• 分子量: 1445.36
• InChiKey: OPHHEKNPPAPUKT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  OsH2(PPh(OEt)2)4 、 四苯硼钠 、 丁炔二酸二甲酯 、 三氟甲烷磺酸甲酯 以 乙醚 为溶剂， 以>=75的产率得到[Os(C(COOMe)=CHCOOMe)(P(OEt)2Ph)4]BPh4
  参考文献：
  名称：

  Synthesis and characterisation of enynyl, vinyl and acetylide complexes of osmium(II)

  摘要：

  Treatment of [OsH(2)L(4)] [L = P(OEt)(3) or PPh(OEt)(2)] first with CF(3)SO(3)Me and then with an excess of terminal alkynes RC-CM (R = Bu(t), Ph or p-MeC(6)H(4)) produced enynyl derivatives [Os{eta(3)-RC(3)C(H)R}L(4)](+) 1-3. Sequential reactions of [OsH(2)L(4)] with CF(3)SO(3)Me and activated alkynes R'O2CC=CH (R' = Me or Et) or MeO(2)CC=CCO(2)Me yielded alkenyl [Os{CH=C(H)CO(2)R')L(4)](+) 4,5 and [Os{C(CO(2)Me)=C(H)CO2- Me}L(4)](+) 6 cations, respectively. Spectroscopic data (IR, H-1, P-31, C-13 NMR) suggest, in the case of L = P(OEt)(3), the presence of two isomers for the alkenyls 4 and 5, with five- and four-membered, chelate rings of the vinyl ligand. Hydride-alkynyl [OsH(C=CPh)L(4)] complexes were also obtained by treating[OsH(2)L(4)] with CF(3)SO(3)Me followed by treatment with lithium phenylacetylide.

  DOI：

  10.1039/dt9950000719