4-[[2-(4-氯苯基)-2-甲基丙氧基]甲基]-1-氟-2-苯氧基苯 | 83492-86-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-[[2-(4-氯苯基)-2-甲基丙氧基]甲基]-1-氟-2-苯氧基苯
• 英文名称: 3-phenoxy-4-fluorobenzyl 2-(4-chlorophenyl)-2-methylpropyl ether
• 英文别名: Benzene, 4-((2-(4-chlorophenyl)-2-methylpropoxy)methyl)-1-fluoro-2-phenoxy-；4-[[2-(4-chlorophenyl)-2-methylpropoxy]methyl]-1-fluoro-2-phenoxybenzene
• CAS: 83492-86-8
• 化学式: C₂₃H₂₂ClFO₂
• 分子量: 384.878
• InChiKey: RKFZFWKPMXSTJD-UHFFFAOYSA-N

物化性质

• 沸点：
  446.4±45.0 °C(Predicted)
• 密度：
  1.178±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  氟醚醇 在 sodium hydroxide 、 二甲基亚砜 作用下， 以 水 为溶剂， 以77%的产率得到4-[[2-(4-氯苯基)-2-甲基丙氧基]甲基]-1-氟-2-苯氧基苯
  参考文献：
  名称：

  2-aryl-ethyl ether derivatives and insecticidal and acaricidal agents

  摘要：

  本发明涉及由以下一般式[I]表示的2-芳基乙基醚或硫醚衍生物：##STR1##其中Ar代表芳基，R.sup.1代表1至6个碳原子的直链或支链烷基，R.sup.2代表氢原子，或甲基或乙基基团，R.sup.3代表卤素原子，或甲基或甲氧基，R.sup.4代表氢原子或卤素原子，或较低烷基或较低烷氧基团，n是1或2的整数，但当n为2时，基团R.sup.4可以相同也可以不同，Y代表氧原子或硫原子，以及制备这些醚或硫醚的方法和这些醚或硫醚的用途。本发明的这些化合物具有出色的杀虫和杀螨活性，而这些化合物的毒性非常低。

  公开号：

  US04599362A1

文献信息

• Novel pyrazoline compounds, process for production thereof, and insecticides containing them as active ingredients
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0207728A2

  公开（公告）日：1987-01-07

  Novel pyrazoline compounds of the general formula wherein X represents a hydrogen or halogen atom or a methyl or methylsulfonyloxy group, Y represents a hydrogen or halogen atom or a trifluoromethyl group, Z represents an oxygen or sulfur atom, and A represents an oxygen atom or -NH-, which are useful as an insecticide. These compounds are produced by reacting a compound represented by the

  通式如下的新型吡唑啉化合物 其中 X 代表氢原子或卤素原子或甲基或甲磺酰氧基，Y 代表氢原子或卤素原子或三氟甲基，Z 代表氧原子或硫原子，A 代表氧原子或-NH-，可用作杀虫剂。这些化合物是通过使由
• Insecticidal resin coating film
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0257415A1

  公开（公告）日：1988-03-02

  An insecticidal resin coating film comprising a combination of an acrylonitrile and/or methacrylonitrile copolymer resin and an insecticidal component selected from the group consisting of specified compounds exhibits an insecticidal effect, since the compound is kept on the surface of the coating film in a state capable of exhibiting its insecticidal effect for a long period of time.

  杀虫树脂涂膜由丙烯腈和/或甲基丙烯腈共聚物树脂和从特定化合物组成的组中选出的杀虫成分组合而成，具有杀虫效果，因为化合物在涂膜表面保持的状态能够长时间显示其杀虫效果。
• Dialkoxymethylimidazolidine derivatives, preparation thereof, insecticides containing same as an effective ingredient and intermediates therefor
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0455000A1

  公开（公告）日：1991-11-06

  Dialkoxymethylimidazolidine derivatives of the formula (1) wherein Z represents a 2-chloropyridin-5-yl group or a 2-chlorothiazol-5-yl group, R₁ and R₂, respectively, represent a lower alkyl group having from 1 to 6 carbon atoms, or a lower haloalkyl group having from 1 to 3 carbon atoms or a lower alkyl group having from 1 to 3 carbon atoms and substituted with a lower alkoxy group having from 1 to 3 carbon atoms, or R₁ and R₂are joined to form a cyclic alkylene group having from 2 to 3 carbon atoms, and n is a value of 2 or 3, are described. Also, a preparation process of the derivatives and insecticidal compositions comprising the same are set forth. In addition, novel intermediate compounds of the formula (2) useful in preparing the derivatives of the formula (1) are also described along with their preparation process

  式（1）的二烷氧基甲基咪唑烷衍生物 其中 Z 代表 2-氯吡啶-5-基团或 2-氯噻唑-5-基团，R₁ 和 R₂ 分别代表具有 1 至 6 个碳原子的低级烷基、或具有 1 至 3 个碳原子的低级卤代烷基，或具有 1 至 3 个碳原子并被具有 1 至 3 个碳原子的低级烷氧基取代的低级烷基，或 R₁ 和 R₂ 连接形成具有 2 至 3 个碳原子的环烯基，且 n 的值为 2 或 3。此外，还阐述了这些衍生物的制备工艺和包含这些衍生物的杀虫组合物。此外，还介绍了用于制备式（1）衍生物的新型式（2）中间体化合物及其制备工艺。
• Imidazolidine derivatives, preparation thereof, insecticides containing same as an effective ingredient and intermediates therefor
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0490323A1

  公开（公告）日：1992-06-17

  Herein disclosed are novel imidazolidine derivatives of the formula (I) and intermediates of the formula (II) wherein each R represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, a halogen atom, an alkoxy group having from 1 to 6 carbon atoms, a methylenedioxy group, an alkylthio group having from 1 to 4 carbon atoms, a haloalkyl group having from 1 to 2 carbon atoms, a haloalkoxy group having from 1 to 4 carbon atoms, an alkylcarbonyl group having from 1 to 6 carbon atoms, an alkoxycarbonyl.group having from 1 to 6 carbon atoms, a hydroxy group, a cyano group, a nitro group, an alkylamino group having from 1 to 8 carbon atoms, a phenyl group, a phenoxy group, a benzyl group or a halopyridylmethyloxy group, and n is an integer of from 1 to 3, wherein R and n have, respectively, the same meanings as defined above. Processes for preparing the compounds of the formulas (I) and (II) are also described. Moreover, insecticidal compositions comprising an effective amount of the derivative (I) are described.

  这里公开的是式 (I) 的新型咪唑烷衍生物和式 (II) 的中间体 其中每个 R 代表氢原子、具有 1 至 6 个碳原子的烷基、卤素原子、具有 1 至 6 个碳原子的烷氧基、亚甲基二氧基、具有 1 至 4 个碳原子的烷硫基、具有 1 至 2 个碳原子的卤代烷基、具有 1 至 4 个碳原子的卤代烷氧基、具有 1 至 6 个碳原子的烷基羰基、具有 1 至 6 个碳原子的烷氧基羰基、羟基、氰基、烷氧基羰基。1至6个碳原子的烷基羰基、烷氧基羰基、羟基、氰基、硝基、1至8个碳原子的烷基氨基、苯基、苯氧基、苄基或卤代吡啶基甲氧基，n为1至3的整数、 其中 R 和 n 分别具有与上述定义相同的含义。还描述了制备式（I）和（II）化合物的工艺。此外，还描述了包含有效量衍生物 (I) 的杀虫组合物。
• ——
  作者：NAKATANI KIYOSHI、 NUMATA SATOSHI、 INOUE TSUNEO、 HOSONO AKIRA、 ODA KENGO、 +

  DOI：——

  日期：——