1H-Furo[3,4-f]indole-5,7-dione,8,8a-dihydro-4,8,8,8a-tetramethyl-1,2-diphenyl- | 139118-38-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯啉
• 英文名称: 1H-Furo[3,4-f]indole-5,7-dione,8,8a-dihydro-4,8,8,8a-tetramethyl-1,2-diphenyl-
• 英文别名: 4,8,8,8a-Tetramethyl-1,2-diphenyl-8,8a-dihydro-1H-furo[3,4-f]indole-5,7-dione
• CAS: 139118-38-0
• 化学式: C₂₆H₂₃NO₃
• 分子量: 397.474
• InChiKey: FVIGJNAAQJBODH-UHFFFAOYSA-N

物化性质

• 沸点：
  589.8±50.0 °C(Predicted)
• 密度：
  1.28±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.04
• 重原子数：
  30.0
• 可旋转键数：
  2.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  46.61
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  1H-Furo[3,4-f]indole-5,7-dione,8,8a-dihydro-4,8,8,8a-tetramethyl-1,2-diphenyl- 生成 (E)-α-1,5-diphenyl-3-pyrrylethylidene(isopropylidene)succinic anhydride
  参考文献：
  名称：

  Studies on Photochromic Mechanism And Applications of Pyrryl Substituted Fulgides

  摘要：

  A series of pyrryl substituted fulgides have been designed and synthesized. Photochromic properties of fulgides have been investigated in various organic solvents. Photochromic mechanism of this kind of fulgides have been studied by means of nanosecond laser flash photolysis technique, both of excited singlet and excited triplet state are involved in the photocyclization process. A sample of optical disk was prepared by spin coating method. Photoinduced electron transfer between pyrryl fulgide and TCNQ has been found and studied by UV-Vis and EPR spectroscopic techniques.

  DOI：

  10.1080/10587259408037787
• 作为产物：
  描述：

  (E)-α-1,5-diphenyl-3-pyrrylethylidene(isopropylidene)succinic anhydride 生成 1H-Furo[3,4-f]indole-5,7-dione,8,8a-dihydro-4,8,8,8a-tetramethyl-1,2-diphenyl-
  参考文献：
  名称：

  Studies on Photochromic Mechanism And Applications of Pyrryl Substituted Fulgides

  摘要：

  A series of pyrryl substituted fulgides have been designed and synthesized. Photochromic properties of fulgides have been investigated in various organic solvents. Photochromic mechanism of this kind of fulgides have been studied by means of nanosecond laser flash photolysis technique, both of excited singlet and excited triplet state are involved in the photocyclization process. A sample of optical disk was prepared by spin coating method. Photoinduced electron transfer between pyrryl fulgide and TCNQ has been found and studied by UV-Vis and EPR spectroscopic techniques.

  DOI：

  10.1080/10587259408037787

文献信息

• Harris, Stuart A.; Heller, Harry G.; Oliver, Stephen N., Journal of the Chemical Society. Perkin transactions I, 1991, # 12, p. 3259 - 3262
  作者：Harris, Stuart A.、Heller, Harry G.、Oliver, Stephen N.

  DOI：——

  日期：——