tert-butyldimethyl((5(tributylstannyl)thiophen-2-yl)methoxy)silane | 1339222-92-2

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: tert-butyldimethyl((5(tributylstannyl)thiophen-2-yl)methoxy)silane
• CAS: 1339222-92-2
• 化学式: C₂₃H₄₆OSSiSn
• 分子量: 517.479
• InChiKey: OTXKNCCDBKWBAY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.33
• 重原子数：
  27.0
• 可旋转键数：
  13.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  tert-butyldimethyl((5(tributylstannyl)thiophen-2-yl)methoxy)silane 、 2-bromo-3,5-dimethyl-6-phenyl-dithieno[3,2-b:2',3'-d]thiophene-4,4-dioxide 在 四(三苯基膦)钯 作用下， 以 甲苯 为溶剂， 反应 1.0h， 生成
  参考文献：
  名称：

  Live-Cell-Permeant Thiophene Fluorophores and Cell-Mediated Formation of Fluorescent Fibrils

  摘要：

  In our search for thiophene fluorophores that can overcome the limits of currently available organic dyes in live-cell staining, we synthesized biocompatible dithienothiophene-S,S-dioxide derivatives' (DTTOs). that were spontaneously taken up by live mouse embryonic fibroblasts and HeLa cells. Upon treatment with DTTOs, the cells secreted nanostructured fluorescent fibrils, while cell viability remained unaltered. Comparison with the behavior of Other cell-permeant, newly synthesized thiophene fluorophores showed that the formation of fluorescent fibrils was peculiar to DTTO dyes. Laser scanning confocal microscopy of the fluorescent fibrils showed that most of them were characterized by helical supramolecular organization. Electrophoretic analysis and theoretical calculations suggested that the DTTOs were selectively recognized by the HyPro component of procollagen polypeptide chains and incorporated through the formation of multiple H-bondings.

  DOI：

  10.1021/ja2065522

文献信息

• Pi‐conjugated chain extenders for the synthesis of optoelectronic segmented polyurethanes
  作者：Christopher P. Harvey、John D. Tovar

  DOI：10.1002/pola.24937

  日期：2011.11.15

  optical properties of mechanochromic materials change under mechanical stress. Segmented polyurethanes are elastomers composed of amorphous, saturated chain soft segments, and rigid pi‐conjugated hard domains. Within aggregates of hard domains pi–pi interactions may form and result in perturbation of the optoelectronic properties of the system. Disruption and restoration of these electronic interactions

  机械致变色材料的光学性质会在机械应力下发生变化。嵌段聚氨酯是由无定形，饱和链软链段和刚性π共轭硬区组成的弹性体。在硬域的聚集体中，pi-pi相互作用可能形成并导致系统光电特性的扰动。材料中这些电子相互作用的破坏和恢复可能导致可观察到的机械变色响应。已经合成了一系列的低聚噻吩二醇和二胺，以及萘二酰亚胺二醇，以使用长的聚四氢呋喃链作为软链段掺入到分段的聚氨酯和聚脲的硬质区域中。评价所得聚合物以确定其聚合程度和其热稳定性。在溶液和薄膜中研究了材料的光学性质。在可能的情况下，还研究了聚合物的电化学性能。嵌段聚氨酯中软链段的长度阻碍了硬结构域的电子偶联。涉及更小，更可溶的软链段的未来工作可能使材料表征和机械变色响应更容易。©2011 Wiley Periodicals，Inc. J Polym Sci A部分：Polym Chem，2011年。溶解度更高的软链段可以使材料表征和机械变色响应更容易。©2011