Sn(SC6H4NH2-o)2I2 | 369361-56-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: Sn(SC6H4NH2-o)2I2
• 英文别名: 2-[(2-aminophenyl)sulfanyl-diiodostannyl]sulfanylaniline
• CAS: 369361-56-8
• 化学式: C₁₂H₁₂I₂N₂S₂Sn
• 分子量: 620.892
• InChiKey: VJPVYRDHSZMCLV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tin 、 碘 、 双(2-氨基苯基)二硫 以 甲苯 为溶剂， 以82%的产率得到Sn(SC6H4NH2-o)2I2
  参考文献：
  名称：

  SYNTHESIS OF NEW TIN(IV) COMPOUNDS OF SUBSTITUTED DIPHENYLSULFIDE DERIVATIVES AND THEIR COMPLEXES WITH SOME NEUTRAL LIGANDS

  摘要：

  Some new tin(IV) compounds of the general formula Sn(SC6H4R)(4), where R = o-NH2, p-Me, p-Bu-t have been obtained from the direct reaction of (RC6H5S)(2) and tin metal in the molar ratio 2:1 in refluxing toluene. Similarly, a mixture of tin (RC6H5S)(2) and iodine in 1.0: 1.5:0.5 or 1.0: 1.0: 1.0 molar ratios in refluxing toluene leads to the formation of Sn(SC6H4R)(3)I or Sn(SC6H4R)(2)](2), respectively, Complexes of the new tin compounds with triphenylphosphine, 4-picoline, 1,10-phenanthroline and 2,2'-bipyridine have been synthesized by the direct reaction between the tin compound and the neutral ligand. The tin compounds and their adducts have been characterized physio-chemically and spectroscopically.

  DOI：

  10.1081/sim-100104854