| 259752-65-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 259752-65-3；260047-55-0；260047-56-1
• 化学式: C₁₂H₁₈BBr₂P
• 分子量: 363.868
• InChiKey: QCTYNKVKCGAGCK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.65
• 重原子数：
  16.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  在 lithium 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 16.5h， 生成 3,4-Bis-[(diphenylphosphanyl)-methyl]-1-phenyl-phospholane
  参考文献：
  名称：

  Cyclo and Spirozirconation: Synthesis of New Phospholane-Boranes and Polyphosphine-Boranes

  摘要：

  The diallylic phosphine-borane Ph(BH3)P(allyl)(2) 6, reacts with the zirconocene 'Cp2Zr' and gives the bicyclocomplex intermediate 7, characterized by H-1 and P-31 NMR. The electrophilic addition of H+, Br-2, PhPCl2(BH3), Ph2PCl(BH3) leads to the corresponding stabilized phospholanes 8, 9, 11 and bicyclophospholane 10, whereas Ph2P(BH3)Li on 9 gives the boro(phospholane-diphosphine) 12. Under the same conditions, the tetraallylsilane (or germane) 13a-b leads to the spirometallacyclopentane 14a-b intermediates. After reaction with Br-2, Ph2PLi(BH3) and PhPCl2(BH3), the racemic spirannic tetraphosphines 16a-b and the protected spirannic diphosphine 17b are obtained with a remarkable selectivity. Decomplexation reaction by Et2NH gives corresponding free phosphines 3'-17'. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00780-2
• 作为产物：
  描述：

  diallylphenylphosphino-borane 在 正丁基锂 、 二氯二茂锆 、 溴 作用下， 以 四氢呋喃 、 四氯化碳 为溶剂， 反应 12.0h， 生成
  参考文献：
  名称：

  Cyclo and Spirozirconation: Synthesis of New Phospholane-Boranes and Polyphosphine-Boranes

  摘要：

  The diallylic phosphine-borane Ph(BH3)P(allyl)(2) 6, reacts with the zirconocene 'Cp2Zr' and gives the bicyclocomplex intermediate 7, characterized by H-1 and P-31 NMR. The electrophilic addition of H+, Br-2, PhPCl2(BH3), Ph2PCl(BH3) leads to the corresponding stabilized phospholanes 8, 9, 11 and bicyclophospholane 10, whereas Ph2P(BH3)Li on 9 gives the boro(phospholane-diphosphine) 12. Under the same conditions, the tetraallylsilane (or germane) 13a-b leads to the spirometallacyclopentane 14a-b intermediates. After reaction with Br-2, Ph2PLi(BH3) and PhPCl2(BH3), the racemic spirannic tetraphosphines 16a-b and the protected spirannic diphosphine 17b are obtained with a remarkable selectivity. Decomplexation reaction by Et2NH gives corresponding free phosphines 3'-17'. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00780-2