ω-(2-ketopyridyl-1)-n-octadecane | 51283-27-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: ω-(2-ketopyridyl-1)-n-octadecane
• 英文别名: N-stearyl pyridone；1-octadecylpyridin-2-one
• CAS: 51283-27-3
• 化学式: C₂₃H₄₁NO
• 分子量: 347.585
• InChiKey: JQHDEYSXBYMYNJ-UHFFFAOYSA-N

物化性质

• 沸点：
  484.8±14.0 °C(Predicted)
• 密度：
  0.909±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  25
• 可旋转键数：
  17
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  十八胺 、 氰乙酸乙酯 、 乙酰乙酸乙酯 、 哌啶 、 、 盐酸 在 甲醇 作用下， 以 水 、 甲醇 、 乙二醇二甲醚 、 甲苯 为溶剂， 反应 49.0h， 以to afford 24.5 grams (0.061 mol, 87 percent yield) of N-stearyl pyridone product as light tan powder的产率得到ω-(2-ketopyridyl-1)-n-octadecane
  参考文献：
  名称：

  DIMERIC AZO PYRIDONE COLORANTS

  摘要：

  公开的是式子1的化合物。这些化合物可用作染料，特别是在相变墨水等应用中。

  公开号：

  US20040010058A1

文献信息

• DIMERIC AZO PYRIDONE COLORANTS
  申请人：Xerox Corporation

  公开号：US20040010058A1

  公开（公告）日：2004-01-15

  Disclosed are compounds of the formula 1 The compounds are useful as colorants, particularly in applications such as phase change inks.

  公开的是式子1的化合物。这些化合物可用作染料，特别是在相变墨水等应用中。
• PROCESS FOR PREPARING SUBSTITUTED PYRIDONE COMPOUNDS
  申请人：Xerox Corporation

  公开号：US20040006234A1

  公开（公告）日：2004-01-08

  Disclosed is a process for preparing substituted pyridone compounds which comprises (a) admixing in the absence of a solvent (1) an amine of the formula R 1 —NH 2 wherein R 1 is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and (2) a first ester of the formula 1 wherein R 2 is an electron withdrawing group and R 3 is an alkyl group; (b) heating the mixture containing the amine and the first ester to form an intermediate compound of the formula 2 (c) admixing the intermediate compound with (1) a base and (2) a second ester of the formula 3 wherein R 4 is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group and R 5 is an alkyl group, said second ester being present in a molar excess relative to the intermediate compound, said base being present in a molar excess relative to the intermediate compound, and (d) heating the mixture containing the intermediate compound, the second ester, and the base to form a pyridone compound of the formula 4 or a salt thereof. Also disclosed is a process for preparing diazopyridone colorants which comprises preparing a pyridone compound by the above process and reacting the pyridone compound with a diazonium salt to form a diazopyridone compound.

  本发明公开了一种制备取代吡啶酮化合物的方法，其包括(a)在无溶剂的情况下混合(1)式为R1-NH2的胺，其中R1为烷基，芳基，芳基烷基或烷基芳基基团，以及(2)式为1的第一酯，其中R2为电子提取基团，R3为烷基；(b)加热含有胺和第一酯的混合物，以形成式为2的中间化合物；(c)混合中间化合物与(1)碱和(2)式为3的第二酯，其中R4为烷基，芳基，芳基烷基或烷基芳基基团，R5为烷基，所述第二酯相对于中间化合物存在摩尔过量，碱相对于中间化合物存在摩尔过量；(d)加热含有中间化合物，第二酯和碱的混合物，以形成式为4的吡啶酮化合物或其盐。本发明还公开了一种制备重氮吡啶酮染料的方法，其包括通过上述方法制备吡啶酮化合物，并将吡啶酮化合物与重氮盐反应，以形成重氮吡啶酮化合物。
• Phase change inks containing azo pyridone colorants
  申请人：Xerox Corporation

  公开号：US20040007155A1

  公开（公告）日：2004-01-15

  Disclosed is a phase change ink composition comprising a phase change ink carrier and a colorant compound of the formula 1

  揭示了一种相变油墨组合物，包括相变油墨载体和化合物1的着色剂化合物。
• Method for making dimeric azo pyridone colorants
  申请人：Xerox Corporation

  公开号：US06576748B1

  公开（公告）日：2003-06-10

  Disclosed is a process for preparing a diazopyridone compound either (A) of the formula or (B) of the formula which comprises diazotizing a dianiline and coupling it with a pyridone or diazotizing an aniline and coupling it with a dipyridone.

  本发明公开了一种制备二氮杂吡啶酮化合物的方法，其中化合物(A)的化学式或化合物(B)的化学式，包括将二苯胺重氮化并与吡啶酮偶联，或将苯胺重氮化并与二吡啶酮偶联。
• Processes for preparing dianthranilate compounds and diazopyridone colorants
  申请人：Xerox Corporation

  公开号：US06576747B1

  公开（公告）日：2003-06-10

  Disclosed is a process for preparing dianthranilate compounds which comprises (a) admixing reactants as follows: (1) a diol of the formula R1(OH)2, wherein R1 is an alkylene group having at least about 20 carbon atoms, and wherein the —OH groups are primary or secondary, (2) isatoic anhydride, present in an amount of at least, about 2 moles of isatoic anhydride per every one mole of diol, (3) a catalyst which is 1,4-diazabicyclo [2.2.2]octane, N,N,N′,N′-tetramethylethylene diamine, or a mixture thereof, said catalyst being present in an amount of at least about 0.2 mole of catalyst per every one mole of diol, and (4) a solvent; and (b) heating the mixture thus formed to form a dianthranilate compound of the formula Also disclosed is a process for preparing diazopyridone colorants which comprises (I) preparing a dianthranilate compound by the aforementioned method, (II) reacting the dianthranilate compound with nitrosylsulfuric acid to form a diazonium salt, and (III) reacting the, diazonium salt with a pyridone compound to form a diazopyridone compound.

  本发明揭示了一种制备二芳酰氨化合物的方法，包括(a)混合以下反应物：(1)式为R1(OH)2的二元醇，其中R1是至少具有约20个碳原子的烷基基团，且—OH基团为一级或二级，(2)异香草酸酐，其量至少为每摩尔二元醇2摩尔的量，(3)催化剂，该催化剂为1,4-二氮杂双环[2.2.2]辛烷，N,N,N′,N′-四甲基乙二胺或它们的混合物，催化剂的量至少为每摩尔二元醇0.2摩尔的量，以及(4)溶剂；(b)加热所形成的混合物，以形成式为的二芳酰氨化合物。本发明还揭示了一种制备二氮杂吡咯酮染料的方法，包括(I)通过上述方法制备二芳酰氨化合物，(II)将二芳酰氨化合物与硝酰硫酸反应形成重氮盐，以及(III)将重氮盐与吡咯酮化合物反应形成二氮杂吡咯酮化合物。