| 1394016-63-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1394016-63-7
• 化学式: C₅₀H₃₂N₉O₈P₃
• 分子量: 979.781
• InChiKey: GIUOZXQFEORQPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.3
• 重原子数：
  70
• 可旋转键数：
  8
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  196
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  、 silver nitrate 以 四氢呋喃 、 甲醇 为溶剂， 反应 72.0h， 以71%的产率得到
  参考文献：
  名称：

  Coordination-driven synthesis of Ag(I) compounds based on a double emission ligand consisting of 1,3,4-oxadiazole and cyclotriphosphazene units

  摘要：

  A new ligand (L) which consists of cyclotriphosphazene and 1,3,4-oxadiazole units is reported. Two new Ag(I) coordination compounds {[Ag(L)SO3CF3](n) (1) and Ag2L2(NO3)(2) (2)} based on L and Ag(I) salts are obtained. Compound 1 features a 1-D chain, in which the ligand L adopts a divergent trans-conformation, whereas 2 is a discrete binuclear Ag(I) molecule in which L adopts convergent cis-conformation. Compounds 1 and 2 are fully characterized by H-1-NMR, Infrared, elemental analysis, X-ray powder, and single-crystal diffraction. Luminescent properties of 1 and 2 are investigated.

  DOI：

  10.1080/00958972.2012.700053
• 作为产物：
  描述：

  2,2-dichloro-4,4,6,6-bis[spiro(2',2''-dioxy-1'',1''-biphenyl)]cyclotriphosphazene 、 2-(5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl)phenol 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 以60.8%的产率得到
  参考文献：
  名称：

  Coordination-driven synthesis of Ag(I) compounds based on a double emission ligand consisting of 1,3,4-oxadiazole and cyclotriphosphazene units

  摘要：

  A new ligand (L) which consists of cyclotriphosphazene and 1,3,4-oxadiazole units is reported. Two new Ag(I) coordination compounds {[Ag(L)SO3CF3](n) (1) and Ag2L2(NO3)(2) (2)} based on L and Ag(I) salts are obtained. Compound 1 features a 1-D chain, in which the ligand L adopts a divergent trans-conformation, whereas 2 is a discrete binuclear Ag(I) molecule in which L adopts convergent cis-conformation. Compounds 1 and 2 are fully characterized by H-1-NMR, Infrared, elemental analysis, X-ray powder, and single-crystal diffraction. Luminescent properties of 1 and 2 are investigated.

  DOI：

  10.1080/00958972.2012.700053