(Z)-3-((4-(decyloxy)phenyl)amino)-1-(4-(nonyloxy)phenyl)prop-2-en-1-one | 371112-63-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: (Z)-3-((4-(decyloxy)phenyl)amino)-1-(4-(nonyloxy)phenyl)prop-2-en-1-one
• CAS: 371112-63-9
• 化学式: C₃₄H₅₁NO₃
• 分子量: 521.784
• InChiKey: KCWAUVBFAAWMJZ-RQZHXJHFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.14
• 重原子数：
  38.0
• 可旋转键数：
  23.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  47.56
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  (Z)-3-((4-(decyloxy)phenyl)amino)-1-(4-(nonyloxy)phenyl)prop-2-en-1-one 、 lanthanum(III) nitrate hexahydrate 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Liquid crystalline N-aryl-β-aminovinyl ketones and their complexes with lanthanides

  摘要：

  Liquid crystalline lanthanide complexes with N-aryl-substituted beta-aminovinyl ketones were synthesized for the first time. The complexes give rise to smectic A mesophase and are stable only in the solid state; in going to solution, they dissociate with formation of the initial ligand.

  DOI：

  10.1134/s1070363206070152
• 作为产物：
  描述：

  nonyl phenyl ether 在 高氯酸 、 sodium 作用下， 以 乙醇 、 苯 为溶剂， 反应 5.67h， 生成 (Z)-3-((4-(decyloxy)phenyl)amino)-1-(4-(nonyloxy)phenyl)prop-2-en-1-one
  参考文献：
  名称：

  Liquid crystalline N-aryl-β-aminovinyl ketones and their complexes with lanthanides

  摘要：

  Liquid crystalline lanthanide complexes with N-aryl-substituted beta-aminovinyl ketones were synthesized for the first time. The complexes give rise to smectic A mesophase and are stable only in the solid state; in going to solution, they dissociate with formation of the initial ligand.

  DOI：

  10.1134/s1070363206070152

文献信息

• ——
  作者：O. A. Turanova、Yu. G. Galyametdinov、I. V. Ovchinnikov

  DOI：10.1023/a:1011390622121

  日期：——

  Mesogenic complexes were synthesized by the reaction of beta -aminovinyl ketones with copper(II) acetate. On going from the ligands to complexes, the temperature of phase transitions increases and the nematic phase disappears. The initial members of the homological 1-(4-nonyloxyphenyl)-3-(4-methoxyphenylamino)-1-propen-1-one series demonstrate the alternation of clearing temperatures, which is absent for the corresponding copper(II) complexes.