4'-(6-methacryloyloxy-1-hexyloxy)biphenyl-4-carboxylic acid | 141085-16-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4'-(6-methacryloyloxy-1-hexyloxy)biphenyl-4-carboxylic acid
• 英文别名: 4-(6-methacryloyloxyhexyloxy)biphenyl-4'-carboxylic acid；4-[4-[6-(2-methylprop-2-enoyloxy)hexoxy]phenyl]benzoic acid
• CAS: 141085-16-7
• 化学式: C₂₃H₂₆O₅
• 分子量: 382.456
• InChiKey: OIXIOZIJTLFMIN-UHFFFAOYSA-N

物化性质

• 沸点：
  555.6±45.0 °C(Predicted)
• 密度：
  1.130±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  28
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  72.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4'-(6-methacryloyloxy-1-hexyloxy)biphenyl-4-carboxylic acid 在 氯化亚砜 作用下， 反应 2.0h， 生成
  参考文献：
  名称：

  A Novel Class of Photo- and Electroactive Polymers Containing Oxadiazole and Amine Moieties in a Side Chain

  摘要：

  A new class of photo- and electroactive polymer materials showing an liquid-crystalline (LC) phase were designed and synthesized: four kinds of polymers with both oxadiazole and arylamine moieties as carrier-transporting groups in the side chain. Among them, the polymers with a dimethylamine and a methylcarbazole moiety show LC phases. Furthermore, all the polymers emitted strong blue fluorescence, and their fluorescent quantum yields were over 0.6. The aligned sample of the polymer with the carbazole moiety emitted polarized fluorescence at room temperature. One-layer type electroluminescent (EL) devices were fabricated by using the polymer with a triphenylamine moiety, which exhibited the highest quantum yield (similar to0.82), and found to emit the EL emission at blue region.

  DOI：

  10.1021/ma021406u
• 作为产物：
  描述：

  4'-羟基联苯-4-羧酸 在 三乙胺 、 potassium iodide 、 potassium hydroxide 作用下， 以 1,4-二氧六环 、 乙醇 为溶剂， 反应 59.0h， 生成 4'-(6-methacryloyloxy-1-hexyloxy)biphenyl-4-carboxylic acid
  参考文献：
  名称：

  EP2460788

  摘要：

  公开号：

文献信息

• METAL COMPLEX, COMPOSITION COMPRISING SAME AND LIGHT-EMITTING ELEMENT USING SAME
  申请人：Ikeda Tomiki

  公开号：US20120298932A1

  公开（公告）日：2012-11-29

  The invention provides a metal complex having a structure represented by the following formula (1): wherein M represents a metal atom such as copper; C 1 and C 2 are each an sp3 carbon atom; A 1 -A 4 each independently represent hydrogen, etc; this is with the proviso that A 1 and A 3 may bond together to form a C4 or greater alkylene group and form a ring together with C 1 and C 2 ; the alkylene group may be optionally substituted; R 0 -R 7 each independently represent hydrogen, etc; Z represents a monovalent monodentate ligand, and p is the number of monodentate ligands, represented by (“valency of central metal atom M” −2).

  该发明提供了一种具有以下式(1)所表示结构的金属配合物：其中M表示金属原子，例如铜；C1和C2分别是sp3碳原子；A1-A4分别独立地表示氢等；但是，A1和A3可以结合形成C4或更大的烷基基团，并与C1和C2一起形成环；烷基基团可以选择性地被取代；R0-R7独立地表示氢等；Z表示单价单齿配体，p是单齿配体的数量，由(“中心金属原子M的价-2”)表示。
• Molecularly Oriented Liquid Crystalline Polymer Films Based on Axis-Selective Photo-Fries Rearrangement
  作者：Nobuhiro Kawatsuki、Hitomi Matsushita、Naoki Shin、Mami Kurita、Mizuho Kondo

  DOI：10.1080/15421406.2013.843257

  日期：2013.1

  Four kinds of liquid crystalline polymers (LCPs) with phenyl benzoate side groups were synthesized and their photoinduced reorientation behavior was investigated using linearly polarized (LP) UV light based on the axis-selective photo-Fries rearrangement and thermally induced self-organization of the mesogenic side groups of the materials. Due to different effect of the axis-selectively photoreacted side groups, reorientation direction and its performance depended on the chemical structure of the side groups. Both alignment ability and the molecular rotation of the photoreacted side groups played an important role in the reorientation behavior.
• [EN] LIQUID CRYSTAL ALIGNMENT AGENT, LIQUID CRYSTAL ALIGNMENT FILM, AND LIQUID CRYSTAL DISPLAY ELEMENT<br/>[FR] AGENT D'ALIGNEMENT DE CRISTAUX LIQUIDES, FILM D'ALIGNEMENT DE CRISTAUX LIQUIDES, ET ÉLÉMENT D'AFFICHAGE À CRISTAUX LIQUIDES<br/>[JA] 液晶配向剤、液晶配向膜及び液晶表示素子
  申请人：NISSAN CHEMICAL IND LTD

  公开号：WO2017170681A1

  公开（公告）日：2017-10-05

  本発明は、配向制御能が安定して生じる光照射量の範囲を拡大させて、品質のよい液晶配向膜を効率よく得られる、液晶配向膜製造用の重合体組成物、具体的には横電界駆動型液晶表示素子用液晶配向膜製造用組成物を提供する。また、本発明は、該組成物から形成される液晶配向剤及び液晶配向膜、並びに該液晶配向膜を有する基板及び液晶表示素子を提供する。本発明は、（Ａ）光反応性を発現する構造及び液晶性を発現する構造を有するポリマーを少なくとも２種；（Ｂ）ジイソシアネート成分及びテトラカルボン酸誘導体から選ばれる少なくとも一種と、ジアミン化合物とを用いて製造された重合体、及び（Ｃ）有機溶媒；を含有する重合体組成物、特に少なくとも２種のポリマーのうち、一方のポリマー（Ａ１）と他方のポリマー（Ａ２）とは互いに光反応性を発現する構造の量が異なる重合体組成物を提供する。