trans-bis[S-benzyl-3-(4-n-octyloxybenzylidene)dithiocarbazato-κ2N3,S'] palladium(II) | 1305330-66-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: trans-bis[S-benzyl-3-(4-n-octyloxybenzylidene)dithiocarbazato-κ2N3,S'] palladium(II)
• CAS: 1305330-66-8
• 化学式: C₄₆H₅₈N₄O₂PdS₄
• 分子量: 933.676
• InChiKey: MHNXLRRHQUKJTN-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  S-benzyl-3-[(4-n-octyloxyphenyl)methylene]dithiocarbazate 、 palladium dichloride 以 甲醇 、 乙醇 为溶剂， 以40%的产率得到trans-bis[S-benzyl-3-(4-n-octyloxybenzylidene)dithiocarbazato-κ2N3,S'] palladium(II)
  参考文献：
  名称：

  Bis[S-benzyl-3-(4-n-octyloxybenzylidene)dithiocarbazato-κ²N³,S′]palladium(II)

  摘要：

  In the title compound, [Pd(C23H29N2OS2)(2)], the Pd-II atom displays the expected square-planar coordination geometry. However, the trans configuration, which allows the Pd-II atom to be located on a crystallographic inversion centre, is unusual with respect to the cis arrangement found in analogous Pd complexes comprising similar N,S-chelating ligands.

  DOI：

  10.1107/s0108270110044008