3,3'-dimethyl-4,4'-diacetylaminobiphenyl | 3546-11-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3'-dimethyl-4,4'-diacetylaminobiphenyl
• 英文别名: N,N’-(3,3’-dimethyl-[1,1’-biphenyl]-4,4’-diyl)diacetamide；N,N'-diacetyl-3,3'-dimethylbenzidine；N,N'-(3,3'-dimethyl-biphenyl-4,4'-diyl)-bis-acetamide；N,N'-(3,3'-Dimethyl-biphenyl-4,4'-diyl)-bis-acetamid；3.3'-Dimethyl-N.N'-diacetyl-benzidin；N.N'-Diacetyl-o-tolidin；N-[4-(4-acetamido-3-methylphenyl)-2-methylphenyl]acetamide
• CAS: 3546-11-0
• 化学式: C₁₈H₂₀N₂O₂
• 分子量: 296.369
• InChiKey: YYWOGMJTPSCQAN-UHFFFAOYSA-N

物化性质

• 熔点：
  312 °C
• 沸点：
  437.96°C (rough estimate)
• 密度：
  1.1499 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2924299090

反应信息

• 作为反应物：
  描述：

  3,3'-dimethyl-4,4'-diacetylaminobiphenyl 在 硝酸 作用下， 生成 5,5'-dimethyl-2,2'-dinitro-benzidine
  参考文献：
  名称：

  Cain; Micklethwait, Journal of the Chemical Society, 1914, vol. 105, p. 1446,1447

  摘要：

  DOI：
• 作为产物：
  描述：

  乙酰胺 、 4,4'-二氨基-3,3'-二甲基联苯 生成 3,3'-dimethyl-4,4'-diacetylaminobiphenyl
  参考文献：
  名称：

  Biehringer; Borsum, Chemische Berichte, 1906, vol. 39, p. 3354

  摘要：

  DOI：

文献信息

• Benzidine derivative and electrophotosensitive material using the same
  申请人：Mita Industrial Co. Ltd.

  公开号：US05550290A1

  公开（公告）日：1996-08-27

  The present invention relates to a benzidine derivative represented by the general formula (1): ##STR1## wherein R.sup.1 to R.sup.6, m and n are as defined in the present specification. The benzidine derivative improves durability and heat resistance of a membrane containing the same while maintaining high hole transferring capability. Therefore, an electrophotosensitive material, which comprises a photosensitive layer containing the benzidine derivative, has high sensitivity and is superior in durability and heat resistance.

  本发明涉及一种由通式（1）表示的苯胺衍生物：其中R.sup.1至R.sup.6，m和n如本说明书中所定义。该苯胺衍生物提高了含有该物质的膜的耐久性和耐热性，同时保持高孔传输能力。因此，包括含有该苯胺衍生物的感光层的电子感光材料具有高灵敏度，并且在耐久性和耐热性方面具有优越性。
• Mesogenic glycidyl amines
  申请人：The Dow Chemical Company

  公开号：US05262509A1

  公开（公告）日：1993-11-16

  Phenoxy resins are disclosed which are prepared from polyglycidyl amines containing one or more mesogenic moieties. The phenoxy resins are useful in the preparation of coatings.

  本发明公开了由含有一个或多个介相基团的聚环氧胺制备的酚醛树脂。这些酚醛树脂在涂料制备中非常有用。
• Mesogenic glycidyl amine blends
  申请人：The Dow Chemical Company

  公开号：US05360884A1

  公开（公告）日：1994-11-01

  Glycidyl amines containing mesogenic moieties result in improved properties when cured. These amines are useful in coatings, adhesives, encapsulants, moldings, laminates, and the like.

  含有介向基团的环氧胺在固化后具有更好的性能。这些胺在涂料、粘合剂、封装材料、模塑件、层压板等方面非常有用。
• Tryptanthrine derivative and electrophotosensitive material
  申请人：MITA INDUSTRIAL CO. LTD.

  公开号：EP0708375A1

  公开（公告）日：1996-04-24

  According to the present invention, there is provided a novel tryptanthrine derivative represented by the formula: wherein R1a, R1b, R1c, R1d, R2a, R2b, R2c, and R2d are the same or different and indicate a hydrogen atom, an alkyl group or a halogenated alkyl group; provided that R1a, R1b, R1c and R1d do not indicate a hydrogen atom, simultaneously. Tryptanthrine and a derivative thereof are suitably used for an electrophotosensitive material because of their excellent electron transferring capability.

  根据本发明，提供了一种由式表示的新型色黄嘌呤衍生物： 其中R1a、R1b、R1c、R1d、R2a、R2b、R2c和R2d相同或不同，表示氢原子、烷基或卤代烷基；但R1a、R1b、R1c和R1d不同时表示氢原子。由于黄嘌呤及其衍生物具有出色的电子传递能力，因此适合用作电致发光材料。
• Electron transporting tryptoanthrinime derivatives
  申请人：MITA INDUSTRIAL CO. LTD.

  公开号：EP0718298A1

  公开（公告）日：1996-06-26

  The present invention provides a tryptoanthrinimine derivative represented by the general formula (Y): wherein RA to RM are as defined. Such a derivative of the general formula (Y) is superior in electron transferring capability. Accordingly, an electrophotosensitive material comprising a photosensitive layer containing this derivative (Y) is superior in sensitivity.

  本发明提供了一种由通式（Y）代表的色蒽醌亚胺衍生物： 其中 RA 至 RM 如所定义。这种通式（Y）的衍生物具有优异的电子转移能力。因此，由含有这种衍生物（Y）的感光层组成的电致发光材料的灵敏度更高。