N-trifluoroacetyl-1,4-dihydrobenzylamine | 1256928-08-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-trifluoroacetyl-1,4-dihydrobenzylamine
• 英文别名: N-trifluoroacetyl-(1,4-cyclohexadien-1-ylmethyl)amine
• CAS: 1256928-08-1
• 化学式: C₉H₁₀F₃NO
• 分子量: 205.18
• InChiKey: VFNPKMUSZAJNPC-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  水合三氯化钌 、 N-trifluoroacetyl-1,4-dihydrobenzylamine 以 乙醇 为溶剂， 以66%的产率得到[((η6-N-trifluoroacetyl-benzylamine)RuCl(μ-Cl))2]
  参考文献：
  名称：

  η6-Arene complexes of ruthenium and osmium with pendant donor functionalities

  摘要：

  Conversion of 4'-(2,5-dihydrophenyl)butanol or N-trifluoroacetyl-2,5-dihydrobenzylamine with MCl3 center dot nH(2)O (M-Ru, Os) affords the corresponding dimeric eta(6)-arene complexes in good to excellent yields. Under similar reaction conditions, the amine functionalized arene precursor 2,5-dihydrobenzylamine yields the corresponding Ru(II) complex. For osmium, HCl induced oxidation leads to formation of [OsCl6](2-) salts. However, under optimized reaction conditions, conversion of the precursor 2,5-dihydrobenzylamine chloride results in clean formation of eta(6)-arene Os(II) complex. X-ray structures of [(eta(6)-benzyl ammonium)(dmso) RuCl2] and (2,5-dihydrobenzyl ammonium) 4[OsCl6](2)confirm the spectroscopic data. High stability towards air and acid as well as enhanced solubility in water is observed for all eta(6)-arene complexes. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.08.008