sodium salt of monomethyl ester of maleic acid | 55141-87-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: sodium salt of monomethyl ester of maleic acid
• 英文别名: sodium ethyl maleate；Monoethyl fumarate sodium salt；sodium;(Z)-4-ethoxy-4-oxobut-2-enoate
• CAS: 55141-87-2
• 化学式: C₆H₇O₄*Na
• 分子量: 166.109
• InChiKey: DWAQONASUJXRFZ-LNKPDPKZSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -4.14
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  66.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  马来酸单乙酯 在 sodium hydroxide 作用下， 以 甲醇 为溶剂， 生成 sodium salt of monomethyl ester of maleic acid
  参考文献：
  名称：

  Komadel, Peter; Holba, Vladislav; Truchlik, Stefan, Collection of Czechoslovak Chemical Communications, 1983, vol. 48, # 5, p. 1305 - 1313

  摘要：

  DOI：

文献信息

• Preparation of cis and trans aconitic acids and their salts
  申请人：Lever Brothers Company

  公开号：US04123458A1

  公开（公告）日：1978-10-31

  Novel polyfunctional compounds and a novel process for their preparation are disclosed. These compounds may be converted into the acid or salt forms of cis and trans aconitic acids as well as into a racemic mixture of isocitric acid, alloisocitric acid and the lactones of isocitric acid and alloisocitric acid and their salts. All of the acid and salt forms produced are useful as metal sequestrants and/or detergent builders. The novel polyfunctional compounds can also be saponified to their corresponding alkali metal salts which, in turn, are also metal ion seqestering agents and detergent builders. The polyfunctional compounds are the reaction products obtained from the reaction of selected salts of monoalkyl esters of maleic acid with selected active hydrogen containing compounds.

  本发明揭示了一种新型多功能化合物及其制备方法。这些化合物可以转化为顺式和反式顺乙烯酸以及异柠檬酸、异柠檬酸、柠檬酸内酯及其盐的混合物。所产生的所有酸和盐形式都可用作金属螯合剂和/或洗涤剂添加剂。这些新型多功能化合物也可以皂化成相应的碱金属盐，这些盐也是金属离子螯合剂和洗涤剂添加剂。这些多功能化合物是从选择的单烷基马来酸盐与选择的活性氢含有化合物反应所得到的反应产物。
• Ester derivatives of 1-halo-1,1,2,3-propane tetracarboxylic acid
  申请人：Lever Brothers Company

  公开号：US04159388A1

  公开（公告）日：1979-06-26

  Novel polyfunctional compounds and a novel process for their preparation are disclosed. These compounds may be converted into the acid or salt forms of cis and trans aconitic acids as well as into a racemic mixture of isocitric acid, alloisocitric acid and the lactones of isocitric acid and alloisocitric acid and their salts. All of the acid and salt forms produced are useful as metal sequestrants and/or detergent builders. The novel polyfunctional compounds can also be saponified to their corresponding alkali metal salts which, in turn, are also metal ion sequestering agents and detergent builders. The polyfunctional compounds are the reaction products obtained from the reaction of selected salts of monoalkyl esters of maleic acid with selected active hydrogen containing compounds.

  本发明揭示了一种新型多功能化合物及其制备方法。这些化合物可以转化为顺式和反式顺柠檬酸的酸或盐形式，以及异柠檬酸、异柠檬酸和异柠檬酸内酯及其盐的混合物。所有产生的酸和盐形式都可用作金属螯合剂和/或洗涤剂添加剂。这些新型多功能化合物还可以皂化为相应的碱金属盐，这些盐也是金属离子螯合剂和洗涤剂添加剂。这些多功能化合物是通过选择的单烷基马来酸盐与选择的活性氢含有化合物反应得到的反应产物。
• Preparation of ester derivatives of polycarboxylic acids
  申请人：Lever Brothers Company

  公开号：US04209636A1

  公开（公告）日：1980-06-24

  Novel polyfunctional compounds and a novel process for their preparation are disclosed. These compounds may be converted into the acid or salt forms of cis and trans aconitic acids as well as into a racemic mixture of isocitric acid, alloisocitric acid and the lactones of isocitric acid and alloisocitric acid and their salts. All of the acid and salt forms produced are useful as metal sequestrants and/or detergent builders. The novel polyfunctional compounds can also be saponified to their corresponding alkali metal salts which, in turn, are also metal ion sequestering agents and detergent builders. The polyfunctional compounds are the reaction products obtained from the reaction of selected salts of monoalkyl esters of maleic acid with selected active hydrogen containing compounds.

  本发明揭示了一种新型多功能化合物及其制备方法。这些化合物可以转化为顺反式顺式-顺式顺反式顺式-异柠檬酸和异柠檬酸的内酯及其盐酸形式的酸或盐形式。所生产的所有酸和盐形式都可用作金属螯合剂和/或洗涤剂添加剂。这种新型多功能化合物还可以皂化成相应的碱金属盐，这些盐也是金属离子螯合剂和洗涤剂添加剂。多功能化合物是从选择的单烷基马来酸盐与选择的含活性氢化合物反应得到的反应产物。
• Novel ester derivatives of polycarboxylic acids and process for making
  申请人：Lever Brothers Company

  公开号：US04218381A1

  公开（公告）日：1980-08-19

  Novel polyfunctional compounds and a novel process for their preparation are disclosed. These compounds may be converted into the acid or salt forms of cis and trans aconitic acids as well as into a racemic mixture of isocitric acid, alloisocitric acid and the lactones of isocitric acid and alloisocitric acid and their salts. All of the acid and salt forms produced are useful as metal sequestrants and/or detergent builders. The novel polyfunctional compounds can also be saponified to their corresponding alkali metal salts which, in turn, are also metal ion sequestering agents and detergent builders. The polyfunctional compounds are the reaction products obtained from the reaction of selected salts of monoalkyl esters of maleic acid with selected active hydrogen containing compounds.

  本发明揭示了一种新型多功能化合物及其制备方法。这些化合物可以转化为顺反异康酸的酸或盐形式，以及异柠檬酸、异柠檬酸、柠檬酸内酯和异柠檬酸内酯及其盐的混合物。所有产生的酸和盐形式均可用作金属螯合剂和/或洗涤剂添加剂。新型多功能化合物还可以皂化为相应的碱金属盐，这些盐也是金属离子螯合剂和洗涤剂添加剂。这些多功能化合物是通过选择的单烷基马来酸盐与选择的活性氢含有化合物反应产生的反应产物。
• Salts of propene 1,1,2,3-tetracarboxylic acid
  申请人：Lever Brothers Company

  公开号：US04273935A1

  公开（公告）日：1981-06-16

  Novel polyfunctional compounds and a novel process for their preparation are disclosed. These compounds may be converted into the acid or salt forms of cis and trans aconitic acids as well as into a racemic mixture of isocitric acid, alloisocitric acid and the lactones of isocitric acid and alloisocitric acid and their salts. All of the acid and salt forms produced are useful as metal sequestrants and/or detergent builders. The novel polyfunctional compounds can also be saponified to their corresponding alkali metal salts which, in turn, are also metal ion sequestering agents and detergent builders. The polyfunctional compounds are the reaction products obtained from the reaction of selected salts of monoalkyl esters of maleic acid with selected active hydrogen containing compounds.

  本发明揭示了一种新型多功能化合物及其制备方法。这些化合物可以转化为顺反异庚二酸的酸或盐形式，以及异柠檬酸、异柠檬酸、柠檬酸内酯和异柠檬酸内酯及其盐的外消旋混合物。所有产生的酸和盐形式都可用作金属螯合剂和/或洗涤剂添加剂。新型多功能化合物也可以皂化为相应的碱金属盐，这些盐也是金属离子螯合剂和洗涤剂添加剂。这些多功能化合物是从选择的单烷基马来酸酯盐与选择的活性氢含有化合物反应得到的反应产物。