| 1332828-09-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1332828-09-7
• 化学式: C₂₃H₂₁NO₄
• 分子量: 375.424
• InChiKey: QLXZDVHMROFVBS-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  4-苯基亚甲基-2,6-二叔丁基-2,5-环己二烯-1-酮 、 在 三甲基膦 作用下， 以 二氯甲烷 为溶剂， 以57 %的产率得到
  参考文献：
  名称：

  Phosphine-Catalyzed γ′-Carbon 1,6-Conjugate Addition of α-Succinimide Substituted Allenoates with Para-Quinone Methides: Synthesis of 4-Diarylmethylated 3,4-Disubstituted Maleimides

  摘要：

  In this paper, an interesting γ′-carbon 1,6-conjugate addition for phosphine-catalyzed α-succinimide substituted allenoates has been disclosed. A wide array of substrates was found to participate in the reaction, resulting in the production of diverse 4-diarylmethylated 3,4-disubstituted maleimides with satisfactory to outstanding yields. Furthermore, a plausible mechanism for the reaction was proposed by the investigators.

  DOI：

  10.3390/molecules29112593
• 作为产物：
  描述：

  N-benzhydrylmaleimide 、 2,3-丁二烯酸乙酯 在 三乙烯二胺 作用下， 以 1,4-二氧六环 为溶剂， 生成
  参考文献：
  名称：

  Phosphine-Catalyzed γ′-Carbon 1,6-Conjugate Addition of α-Succinimide Substituted Allenoates with Para-Quinone Methides: Synthesis of 4-Diarylmethylated 3,4-Disubstituted Maleimides

  摘要：

  In this paper, an interesting γ′-carbon 1,6-conjugate addition for phosphine-catalyzed α-succinimide substituted allenoates has been disclosed. A wide array of substrates was found to participate in the reaction, resulting in the production of diverse 4-diarylmethylated 3,4-disubstituted maleimides with satisfactory to outstanding yields. Furthermore, a plausible mechanism for the reaction was proposed by the investigators.

  DOI：

  10.3390/molecules29112593